Two heterocyclic oximes (E)-N-hydroxy-1-(pyridin-2-yl)methanimine (Hp2ylm) and (E)-N-hydroxy-1-(pyridin-3-yl)methanimine (Hp3ylm) were synthesized from pyridine-2-carbaldehyde and pyridine-3-carbaldehyde, respectively. These oximes were characterized by various spectroscopic tools like UV, IR, MASS and NMR. The inhibition capacity of these oximes against copper corrosion in 0.1 M HNO3 was determined by polarization and impedance spectroscopic studies (EIS). At all concentrations, Hp3ylm exhibited higher inhibition efficiency than Hp2ylm. Attempt was made to illustrate the mechanism of corrosion inhibition by these oximes with the help of adsorption isotherm, scanning electron microscopic (SEM) and quantum chemical studies.

Turning experiments were conducted on a novel aluminum alloy (LM6)/fly ash composite based on the response surface and face centered central composite design methodology. The effects of cutting parameters on surface roughness and tool wear were investigated. Multiple regression models were developed for the responses and the adequacies of the developed models were tested at 95% confidence interval using the analysis of variance (ANOVA) technique. Carbide inserts (Model: CNMG 120408-M5) were used for turning the specimens in a CNC turning machine (model: LT-16). The test for significance of the regression models, the test for significance on individual model coefficients and the lack-of-fit tests were performed using the statistical Design-Expert7.0v software environments. R2 indicated the model significance and the value was more than 97%, revealed that the relation between cutting responses and input parameters held good for more than 97% and the model was adequate.

The present study investigates performance and feasibility of application of low cost cemented carbide insert in dry machining of AISI 52100 steel hardened to (55 ± 1 HRC) which is rarely researched as far as machining of bearing steel is concerned. Machinability studies i.e. flank wear, surface roughness and morphology analysis of chip has been investigated and statistical regression modeling has been developed. The test has been conducted based on Taguchi L16 OA taking machining parameters like cutting speed, feed and depth of cut. It is observed that uncoated cemented carbide insert performs well at some selected runs (Run 1, 5 and 9) which show its feasibility for hard turning applications. The developed serrated saw tooth chip of burnt blue colour adversely affects the surface quality. Adequacy of the developed statistical regression model has been checked using ANOVA analysis (depending on F value, P value and R2 value) and normal probability plot at 95% confidence level. The results of optimal parametric combinations may be adopted while turning hardened AISI 52100 steel under dry environment with uncoated cemented carbide insert.

A new series of transition metal complexes of Co(III), Ni(II) and VO(IV) was synthesized with the bidentate Schiff base ligand (HL) derived from the condensation of 2-amino-3-benzyloxypyridine and 5-bromo salicylaldehyde. The synthesized Schiff base ligand and its metal complexes C1-C6 were structurally characterized by satisfactory elemental analysis, spectral studies such as (Mass, IR, ¹H and ¹³C NMR, conductance measurement, UV-vis and magnetic measurements) and thermal studies. The structure of HL was authenticated by X-ray single-crystal analysis. Hirshfeld surface analysis was carried out to understand the nature of intermolecular contacts, the fingerprint plot provides the information about the percentage contribution. Square-pyramidal geometry is proposed for VO(IV) complexes whereas octahedral geometry for Co(III) and Ni(II) complexes. The Schiff base ligand and its metal complexes have been tested in vitro for their antibacterial activities by using well diffusion method against Gram positive bacteria B. subtilis, S. aureus and Gram negative bacteria S. typhi, E. coli and antifungal activities against A. niger, A. flavus, C. albicans and A. Solani. The antimicrobial activity data show that metal complexes are more potent than the parent ligand.

In reality, the machines may interrupt because of the nature of deterioration of the machines. Thus, it is inevitable to perform maintenance alongside production planning. The preventive maintenance is a schedule of strategic operations that are performed prior to the failure occurring, to retain the system operating at the preferred level of consistency. Thus, preventive maintenance plays a significant role in flow shop scheduling models. With its practical significance, this study addresses a practical three-machine n jobs flow shop-scheduling problem (FSSP) in which machine specific preventive maintenance, where each machine is given with a maintenance schedule is considered. In addition, a practical ordered precedence constraint in which some set of jobs has to process in the specified order irrespective of their processing times is also considered. The problem’s goal is to establish the optimal job sequence and preventive maintenance such that the overall cost of tardiness and preventive maintenance is as minimum as possible. An efficient heuristic approach is designed to tackle the present model, resulting in total cost savings. A comparative analysis is not conducted due to absence of studies on the current problem in the literature. However, Computational experiments are carried out on some test instances and results are reported. The reported results may be useful for future studies.

The purpose of this paper is to explore and integrate the role of human resources with the internal practices of the Indian manufacturing industries towards successful implementation of lean manu-facturing (LM). An extensive literature survey is carried out. An attempt is made to build an ex-haustive list of all the input manifests related to human resources and internal practices necessary for LM implementation, coupled with a similar exhaustive list of the benefits accrued from its suc-cessful implementation. A structural model is thus conceptualized, which is empirically validated based on the data from the Indian manufacturing sector. Hardly any survey based empirical study in India has been found to integrate human resources with the internal processes towards success-ful LM implementation. This empirical research is thus carried out in the Indian manufacturing in-dustries. The analysis reveals six key input constructs and three output constructs, indicating that these constructs should act in unison to maximize the benefits of implementing lean. The structural model presented in this paper may be treated as a guide to integrate human resources with internal practices to successfully implement lean, leading to an optimum utilization of resources. This work is one of the very first researches to have a survey-based empirical analysis of the role of human resources and internal practices of the Indian manufacturing sector towards an effective lean im-plementation.

Decision makers of various disciplines are facing challenges because of vast availability of options in the real world. Even though each and every decision made by a decision maker is being done with a great knowledge and conscience, the decision maker needs suitable support to choose the most favorable option to acquire great results in an agile environment. Supplier selection is imperative for an efficient supply chain management. Many industries are in need of effective decision making tools which aids them in valuable supplier selection. This paper proposes a model using Multi Criteria Decision Making (MCDM) tools viz., Grey Relational Analysis (GRA), Analytical Hierarchy Process (AHP) and Technique for Order Performance by Similarity to Ideal Solution (TOPSIS). GRA is used to shortlist the criteria from the available options, while AHP is used to assign weights to the criteria. The final supplier in the selection process is obtained using TOPSIS. The proposed GRA-AHP-TOPSIS model (GRAHP TOP) is used to analyze and formulate the important criteria and the applicability of the model is tested on a case of a small scale industry located in South India.

Quality decisions are one of the major decisions in inventory management. It affects customer’s demand, loyalty and customer satisfaction and also inventory costs. Every manufacturing process is inherent to have some chance causes of variation which may lead to some defectives in the lot. So, in order to cater the customers with faultless products, an inspection process is inevitable, which may also be prone to errors. Thus for an operations manager, maintaining the quality of the lot and the screening process becomes a challenging task, when his objective is to determine the optimal order quantity for the inventory system. Besides these operational tasks, the goal is also to increase the customer base which eventually leads to higher profits. So, as a promotional tool, trade credit is being offered by both the retailer and supplier to their respective customers to encourage more frequent and higher volume purchases. Thus taking into account of these facts, a strategic production model is formulated here to study the combined effects of imperfect quality items, faulty inspection process, rework process, sales return under two level trade credit. The present study is a general framework for many articles and classical EPQ model. An analytical method is employed which jointly optimizes the retailer’s credit period and order quantity, so as to maximize the expected total profit per unit time. To study the behavior and application of the model, a numerical example has been cited and a comprehensive sensitivity analysis has been performed. The model can be widely applicable in manufacturing industries like textile, footwear, plastics, electronics, furniture etc.

The aim of this paper is to apply the technique for order preference by similarity to ideal solution (TOPSIS) as a multi-criteria decision making tool to form the all-time best World XI Test cricket team while taking into consideration over 2600 cricketers participated in Test matches for more than 100 years of cricket history. From the voluminous database containing the performance of numerous Test cricketers, separate lists are first prepared for different positions in the batting and bowling orders consisting of manageable numbers of candidate alternatives while imposing some constraints with respect to the minimum number of innings played (for batsmen), minimum number of tests played (for wicketkeepers and bowlers), and minimum numbers of runs scored and wickets taken (for all-rounders). The TOPSIS method is later adopted to rank those shortlisted cricketers and identify the best performers for inclusion in the proposed World XI Test team. The best World Test cricket team is thus formed as Alastair Cook (ENG) (c), Sunil Gavaskar (IND), Rahul Dravid (IND) (vc), Sachin Tendulkar (IND), Shivnarine Chanderpaul (WI), Jacques Kallis (SA), Adam Gilchrist (AUS) (wk), Glenn McGrath (AUS), Courtney Walsh (WI), Muttiah Muralitharan (SL) and Shane Warne (AUS).

The uncertainty in the supply chains (SCs) for manufacturing and services firms is going to be, over the coming decades, more important for the companies that are called to compete in a new globalized economy. Risky situations for manufacturing are considered in trying to individuate the optimal positioning of the order penetration point (OPP). It aims at defining the best level of information of the client’s order going back through the several supply chain (SC) phases, i.e. engineering, procurement, production and distribution. This work aims at defining a system dynamics model to assess competitiveness coming from the positioning of the order in different SC locations. A Taguchi analysis has been implemented to create a decision map for identifying possible strategic decisions under different scenarios and with alternatives for order location in the SC levels. Centralized and decentralized strategies for SC integration are discussed. In the model proposed, the location of OPP is influenced by the demand variation, production time, stock-outs and stock amount. Results of this research are as follows: (i) customer-oriented strategies are preferable under high volatility of demand, (ii) production-focused strategies are suggested when the probability of stock-outs is high, (iii) no specific location is preferable if a centralized control architecture is implemented, (iv) centralization requires cooperation among partners to achieve the SC optimum point, (v) the producer must not prefer the OPP location at the Retailer level when the general strategy is focused on a decentralized approach.