This research was carried out in order to evaluate the benefits of date seed powder (DSP) by adding it to bakery products to enhance the nutritional value of these products and maximize the economic value of these wastes. Thus, the contents of the (DSP) were determined from the chemical composition, mineral elements, amino acids, fatty acids, phenols and flavonoids, afterthought DSP were added to the toast bread and crackers with a ratio of 5, 10 and 15 % as substitute of the wheat flour and then the organoleptic properties of these products were evaluated. The findings of these investigations revealed that the (DSP) contains important minerals, essential amino acids, unsaturated fatty acids and antioxidants, and all of these compounds have an effective effect on the health of the body. In addition, the Sensorial evaluation of toast bread and crackers were shown to be acceptable by the judges, and thus the possibility of adding DSP to bakery products.

Glass Fiber Reinforced Polymer (GFRP) is a polymer composite material used in lightweight structures. This study provides insight into achieving robust GFRP H-section short-column spliced connections using bonded, bolted, and hybrid connections. The design specifications for steel splicing connections are based on BS EN 1990 and BS EN 1991 guidelines. Based on the samples subjected to axial loading, factors such as compressive strength, bonding and bearing resistance, compression behavior of the connection, and failure modes of the structure are investigated. The study includes the behavioral characteristics and results of 25 GFRP H-section Spliced connections, with each H-section measuring 152 x 72 x 6.4 mm and standing 350 mm in height. This study also examines the behavior of a composite splice joint made up of steel cover plates and steel bolts that are used to create an ideal non-bearing spliced connection. This model is used to compare to the other models to understand the behavior of spliced joints designed with GFRP cover plates. This paper holds design specifications of connections that have displayed compressive strengths of 82.35 %, 89.82 %, and 92.83 % compared to that of an un-cut GFRP H-section subjected to axial loading.

A series of furan derivatives tebufenozide analogues comprising five compounds (2, 3, 4, 5, and 6) have been designed and synthesized via reaction of N'-phenylfuran-2-carbohydrazide (1) with different acid chlorides. The structures of the synthesized compounds were identified by elemental analyses and spectroscopic data. The analogues compounds have the active center of tebufenozide (mimic) with change of tertiary butylhydrazine by phenylhydrazine. Studying the effect of this change on the toxicological activity against Spodoptera littoralis larvae was performed for three compounds of the synthesized ones. Toxicological activity data showed that compound (3) is more active than compounds (2) and (5)

The study provides the forecasts of expected returns based on cross-sectional estimates from the Fama-Macbeth regressions in the United Kingdom. We collected the data of listed firms on the London Stock Exchange on the DataStream from January 1980 to December 2020. We analyze the data sample by employing three cross-sectional models' ten-year rolling estimates of Fama-Macbeth slopes. The empirical findings demonstrate that an investor can derive a composite estimate of the expected return by integrating various company-specific variables in real-time. Model 1 indicates that the expected-return estimates have a predictive slope for future monthly returns of 95.07%, with a standard error of 0.1981. Moreover, model 2 and model 3 report the predictability of returns are 77.57% and 76.94%. In short, our empirical evidence suggests that investors and stakeholders may consider using model 1 to estimate the cost of equity due to its simplicity and effective prediction capability. Our findings are consistent with trade-off theory and prior literature.

The present work investigates Rotary Friction Welding (RFW) of AA2024 similar joints, where the welding operations were carried out using an adapted device to a column-drilling machine (SUPEMEC J320). This work aims to determine the optimal RFW parameters from an experimental study based on mechanical tests and microscopic observations of weld joints. The best compromise, which offers the highest tensile strength value (499 MPa) corresponds to the joint obtained by using a rotational speed of 2000 rpm, a friction pressure of 12 MPa, and a forging pressure of 17 MPa. The EDX results indicate the presence of the intermetallic compounds (IMCs) in each zone of the weld joints, with varying sizes and a random distribution. This study focuses also on the microscopic analyses of the interface of weld joints and the fracture surfaces that indicates a dominant ductile fracture mode.

The FTIR and Raman spectra of dopamine were also recorded in the spectral region 20 - 4000 cm^-1 and 400 - 4000 cm^-1 respectively. The optimized molecular geometry and fundamental vibration frequencies are interpreted using structural optimizations based on the DFT method. The B3LYP / 6-311G (d, p) was used to determine the calculations of the chemical descriptor. The dopamine (DA) molecule can acquire a maximum charge of 0.513 eV from its environment. To understand the molecular interactions of Dopamine, the MEP is a crucial tool. Nonlinear optical descriptors (NLO) and the lengths, bond angles are also determined by DFT and MP2 methods. The DFT method was used to determine the chemical shifts of ¹H and ¹³C of the product. These constants have been calculated by employing the GIAO (Gauge-Including-Atomic-Orbit), CSGT (Continuous Set of Gauge Transformations) and IGAIM (Individual Gauges for Atoms In Molecules) methods at the B3LYP/6-311G (d, p). The comparison of the theoretical chemical shifts with the experimental ones shows that the CSGT method is the best.

This work is interested with a thermoelastic response in a micro-stretch half-space submerged in an unlimited non-viscous fluid under rotation, the medium is studied using the theory of Green-Naghdi (G-N III) and the model of three-phase-lag (3PHL). The governing equations are formulated in the context of G-N theory and the 3PHL model. Analytical solution to the problem is acquired by utilizing the normal mode method. The magnesium crystal element is utilized as an application to compare the predictions induced by rotation on microstretch thermoelastic immersed in an infinite fluid of G–N theory with those for the 3PHL model. Rotation has been noticed to have a major effect on all physical quantities. Comparisons were also made for three values of wave number b and three values of the real part frequency ω0.

The synthesis, anticancer and antimicrobial properties of novel N-aryl-2-(5-aryltetrazol-2-yl)acetamides were discussed. Novel N-aryl-2H-tetrazoles were synthesized and modified in order to obtain the compounds with a satisfactory pharmacological profile. The structures of target substances were confirmed by using ¹H spectroscopy, mass spectrometry and elemental analysis. Anticancer activity screening was carried out within the framework of Developmental Therapeutic Program of the National Cancer Institute's (DTP, NCI, Bethesda, Maryland, USA). The compounds with significant levels of anticancer activities have been found that can be used for further optimization. The antimicrobial activity of the synthesized substances was evaluated by the value of the MIC and minimum fungicidal and bactericidal concentration. The findings exhibited that the compounds possessed moderate antimicrobial potential.

With the complication of the business environment of commercial economic activity, competition intensifies, which threatens the bankruptcy of enterprises, the prevention of which requires quality monitoring and timely identification of crises using methods of comprehensive assessment and analysis of economic security. This research is aimed at conducting component-by-component and, as a result, integrated assessment of the state of economic security of the enterprise. Methodological research tools include analysis of the main components, causation and vector regression modeling. A resource-functional security model is developed (which consists of partial indicators and components of economic security of business) and a resource-functional approach to calculations is also applied. Using the data of the expert survey, the values of indicators of structural components of economic security of the enterprise are determined. Using the resource-functional approach, the integrated values of sub-indices and the integral values of the general level of economic security of the enterprise are calculated. According to the results of the assessment, it is established that the integrated level of economic security of the enterprise is 7.04 (sufficient level of security). However, the components of economic security identified critically low values, namely - the financial component (0.452), the information component (0.554), the institutional and legal component (0.647). The results of the study are of practical value for the development of technological schemes - algorithms for strengthening the financial, informational and institutional and legal security of the enterprise, making sound (using economic and mathematical tools) management decisions to ensure the trajectory of sustainable economic development.

Natural organic pigments such as carotenoids, betalains, anthocyanins, and carminic acid are notably found as safer food preservatives compared to other harmful synthetic chemicals. Due to glycosylation and acylation, betalains exhibit a broad-spectrum antimicrobial functionality with protection against degenerative diseases. Thus, betalains have been investigated as a potential bacterial inhibitor for food preservative applications. Initially, 36 betalain derivatives have been taken for primary screening using molecular docking. Afterward, the top ten ligands are taken for further study and analysis. The results of Prediction of Activity Spectrum of Substances (PASS) assured the antibacterial capabilities of betalains, and Lipinski's rule-of-five ensures the acceptability of the selected ligands as antibacterial inhibitors. The bacterial pathogens, such as C. botulinum (3FIE), E. coli (2ZWK), and S. typhi (3UU2) are selected for molecular docking by these betalain pigments. Furthermore, ADMET investigations and QSAR studies are performed to check insights into the bacterial inhibition process. Most active and common binding sides were observed at GLY159, ASN165, and SER166 for C. botulinum, at ASP8, LYS40, and TRP50 for E. coli; and at ARG37, GLN5, and ARG74 for S. typhi. The present study clearly shows an excellent insight towards the invention of plant-based new organic inhibitors to face the challenges of bacterial-resistant common food preservatives.