NiO cellulose nanocomposite (NiO-CN) were synthesized by the precipitation method and characterized by X-Ray diffraction (XRD), Transmission Electron Microscope (TEM), Scanning Electron Microscope (SEM), Energy Dispersive X-ray (EDX) analysis, Fourier transform infrared (FTIR) measurements and UV–vis spectroscopy. The particles obtained have an average size of 20-30 nm as shown by TEM analysis. Fourier transform infrared (FTIR) measurements were carried out to identify the possible biomolecules responsible for the capping and stabilization of the nickel oxide nanoparticles synthesized by milk. The presence of elements in the nanoparticles was also analysed by Energy Dispersive X-ray (EDX) analysis. The results of EDX analysis show the weight percentages of C, O, Ni, and N-elements in the synthesized material were 41.65%, 52.49%, 3.81%, and 2.06%, respectively. Scanning Electron Microscope (SEM) has been used to assess the morphology of the nanoparticle. The effects of NiO-cellulose nanocomposite are screened for biological activities like, antibacterial activity was done by the Disc diffusion method. The bacterial organisms used in this study were Bacillus subtilis, Salmonela abony, Staphylococcus aureus and Escherichia coli. The observed inhibition zone for these microorganisms was found to be a minimum of 3.0 mm and a maximum of 22.0 mm. Moreover, This NiO-CN also decreases the 50% load of Leishmania donovani via MTT assay with 25µg/ml concentration after 72 hours incubation.

The increasing population in Indonesia results in the rising demand for consumer goods, including salt. Meanwhile, salt production in Indonesia remains traditional, using direct methods by evaporating seawater in open ponds near the coast, producing a final product called “solar salt”. This process depends on sunlight, air, weather, and seasonal climate conditions. This research aims to analyze the technical, technological, and managerial disparities among traditional solar salt farming businesses operated by local communities across regions in Madura Island—the foremost solar salt-producing region in Indonesia. This study employs primary data collected through surveys conducted during the production season in 2023/2024 in three regencies in Madura: Pamekasan, Sampang, and Sumenep. The structured questionnaires captured the input and output data. Meta-frontier Data Envelopment Analysis (meta-DEA) was applied to assess the technical efficiency of conventional solar salt productions across the research regions. The efficiency analysis revealed that, with the current production methods, solar salt farmers achieved an efficiency rate of 46.98%, with an average technical efficiency of 80.83%. This result shows that the decision-making units (DMUs) can enhance their technical efficiency by 19.07%. Meanwhile, the technology gap ratio (TGR) analysis indicates that Sumenep Regency has the highest TGR value, nearing the threshold of 1, suggesting a relatively low technology gap in this regency. The meta-DEA decomposition indicates that the determinant of the average meta-technical inefficiency among solar salt farmers is the technological disparities, with average technological gap inefficiency (TGI) values surpassing managerial gap inefficiency (MGI) values. Conversely, Sumenep Regency has a larger MGI than TGI value, implying that solar salt farmers in Sumenep possess lower managerial decision-making skills than in other regions. The findings suggest the need to enhance the adoption of the latest production technology innovations to address technological gaps in the research locations.

Sulfated tungstate efficiently catalyzes the cyclodehydration of 1-(2-hydroxyphenyl)-3-aryl-1,3-propanediones to flavones under solvent-free conditions. Utilization of conventional heating, simple reaction conditions, short reaction time, ease of product isolation and purification makes this manipulation very interesting from an economic and environmental perspective. Under these conditions, twelve examples were obtained with good yields (85-94%).

Conveying the products to the customers under optimized circumstances is as crucial for the companies as the production itself. One optimization strategy to consider is transportation with the minimum quantity of vehicles and the selection of courses with the minimum distance between the locations. In other words, it is the examination of the solution to the Vehicle Routing Problem (VRP), particularly the Capacitated VRP (CVRP), which is a more realistic modelization approach. For businesses that perform distribution to customers frequently, such as management work with the coordination of daily distribution, finishing the distribution on time is of great importance. In big cities with complicated roads and many dropping points, this can be achieved by benefiting from the systematic modeling of the CVRP. In this study, the delivery network investigation for one production facility of the Istanbul People's Bread positioned on the Asian side of Istanbul, Türkiye that distributes three times a day will be the focus of interest. The corresponding Asymmetric CVRP (ACVRP) for the facility network and 215 bread-selling buffets with authentic driving distances will be solved with the Genetic Algorithm (GA), and an optimized transportation network will be presented.

A famous cisplatin anticancer agent is one of the most widely used chemotherapeutics for treating several human solid tumors. Toxicity of the normal cell is a life-threatening issue that restricts the therapeutic potential of cisplatin complex as an anticancer drug. Even though every year thousands of cisplatin-based analogs have been prepared, screened, and reported, only very few compounds entered the medical trials. Hence, new research work is still sensible. In the last few years, many mononuclear and polynuclear platinum complexes have been considerably investigated, in vitro and in vivo studies evaluated, with some compounds demonstrating significant anticancer potential. In this review, various mono-metallic and poly-metallic platinum‐based complexes with various derivatives used as ligands that have anticancer potential are defined and numerous typical examples are discussed briefly. Present investigation, numerous mononuclear cisplatin derivatives exhibited greater anticancer potency than the parent cisplatin drug. However, polynuclear cisplatin derivatives showed much better anticancer activity than mononuclear cisplatin analogs against various cancer cell lines.

There is a global trend towards adopting green energy, with solar energy being the primary source derived from solar panel technologies. Solar panels can generate enough power for general and household use. However, to effectively function and serve their purpose, they require regular cleaning and effective maintenance, and robotic cleaning is among the current applicable technologies. This research aims to determine the intention of using solar panel cleaning robots in Thailand for individual solar panel users. The study was hinged on the extended C-TAM-TPB model. The quantitative survey study design was employed using primary data collected from individual solar panel users in their households. 419 respondents were used to collect the data. The C-TAM-TPB model proposed using reliability, validity, and model fitness which employed confirmatory factor analysis (CFA). They adopted structural equation modeling (SEM) in the evaluation of the variables' relationships and study hypotheses. Subjective norms and trust in technology, individual control perception, and awareness of renewable energy significantly and positively affected behavioral intention to use solar panel cleaning robots as indicated by the study. Trust in technology, awareness of renewable energy, and environmental concerns were found to be pivotal mediators to the attitude effect on individual users' intention to act in using solar panel cleaning robots. The authors recommend that to improve the adoption of solar panel cleaning robots; the concerned stakeholders should consider, firstly, enhancing trust in the technology of these robots, which is crucial, focusing on aspects like reliability, privacy, security, and reputation. Secondly, considering the influence of subjective norms, including perceptions from family, friends, colleagues, and experts, is essential. Perceived behavioral control should also be a focal point, encompassing self-efficacy, resources, and complexity. Moreover, increasing awareness of renewable energy and environmental benefits is vital to encourage individual adoption. The research also recommended that to encourage the adoption and use of solar panel cleaning robots, the aspects that should be emphasized include subjective norm, perceived behavior control, trust in technology, and awareness of renewable energy.

This study investigates the relationships between creativity, digital leadership, decision-making quality, and public service performance in Sidoarjo Regency. The primary objective is to examine how creativity and digital leadership influence decision-making quality and, subsequently, public service performance. A quantitative approach utilizing a cross-sectional study design was employed. Data were collected from 200 employees of public service institutions in Sidoarjo Regency using Google Forms and direct interviews. The main variables were assessed using Likert scales, measuring creativity, digital leadership, decision-making quality, and public service performance. The analysis involved descriptive and inferential statistics, including regression analysis and mediation analysis. The findings reveal significant positive relationships between creativity, digital leadership, decision-making quality, and public service performance. Creativity and digital leadership were found to positively impact decision-making quality, which in turn influenced public service performance. The implications suggest that fostering a culture of creativity and digital leadership is crucial for enhancing decision-making quality and, consequently, improving public service performance. Public service managers should invest in initiatives to develop creativity and digital leadership skills among employees and prioritize transparent decision-making processes. Furthermore, the study highlights the need for continuous monitoring and evaluation to ensure sustained improvements in public service delivery. The novelty lies in examining the interplay between creativity, digital leadership, decision-making quality, and public service performance within the context of Sidoarjo Regency, providing valuable insights for public service management in the region.

The aim of this study was to investigate the modifications of the mechanical properties of polypropylene (PP) by incorporating elastomers, while considering the impact on its stiffness. Specifically, the research focused on determining the optimal loading of elastomer to achieve desirable properties and exploring the influence of these processes on the morphology and mechanical behavior of the prepared blends. Thermoplastic elastomers (TPEs) consisting of polypropylene and natural rubber (PP/NR) were prepared using a melt-mixing process, and the mechanical properties of the blends were evaluated. The stress-strain properties of the blends revealed a successful modification of PP, transforming it from a stiff and strong thermoplastic into a stiff and tough thermoplastic elastomer when 10% NR was included in the PP matrix. As the loading of NR increased, a reduction in tensile strength (TS) and modulus (E) of the blends was observed, while elongation at break (EB) increased. The flexural strength of unmodified PP was 45.9 MPa, which decreased with increasing NR loading. Similarly, the impact strength of unmodified PP was 25.8 KJ/m², whereas the values for 10%, 20%, 30%, and 40% NR inclusion were 30.8, 24.3, 20.6, and 15.2 KJ/m², respectively. The melt flow index (MFI) of unmodified PP was 14.1 g/10 min, while the values for 10%, 20%, 30%, and 40% NR inclusion were 19.4, 15.7, 11.6, and 10.2 g/10 min, respectively. The best combination of mechanical properties was observed at 10% NR inclusion in the PP matrix. The micrograph of the blends, as observed from SEM micrographs, supported the modification of PP, resulting in the production of TPE with observable adhesion sites, indicating good compatibility between the components. In a nutshell, a significant 47% increase in impact strength was achieved through the modification process.

Manufacturing companies constantly strive to produce products that promote better competitiveness. In addition, the current business environment requires manufacturing companies to adopt environmentally friendly concepts, which have become a global customer concern. Therefore, companies must inevitably meet environmental protection requirements through ecologically friendly processes and products. Meanwhile, environmentally friendly adoption requires a capital-intensive investment, which doubts the management regarding the investment return. Hence, top management commitment is highly needed to maintain eco-friendly products and contribute to the company's performance. This study examines the role of top management commitment to operational performance through adopting information technology, supply chain integration, and green supply chain management. This study surveyed manufacturing companies that have implemented ISO 14000, as many as 73 companies with criteria of having more than 100 employees. Data is collected using questionnaires directly and online with Google Forms. The results of data processing analysis found that top management commitment influences information technology adoption with a priority scale to maintain competitiveness and strategies that increase competitiveness. Top management commitment through information technology can improve supply chain integration and green supply chain management. In addition, supply chain integration improves green supply chain management and operational performance. Implement environmental-friendly measures by involving external partners to impact operational performance. The results of this study contribute to enriching supply chain management theory by significantly adopting green supply chain management to improve sustainable development and performance. It also makes a practical contribution by providing insight for practitioners to generate added value for customers.

In this study, an Economic Return Quantity (ERQ) model for the Empty Container Reposition (ECR) problem using the reverse logistics (RL) approach is developed. Some of the model’s primary considerations are the return rate that depends on the quantity and quality of the empty container, and the capacity constraints to hold the empty container in the port. The model of ERQ is optimized using an analytical approach. Based on the result of the hypothetical case, the authors examined that the acceptable quality level of reusable containers should be set at 67%, 55%, and 50% for the three types of containers to be able to obtain minimum inventory costs. Two cases of binding and nonbinding constraints are investigated, and it is found that the binding constraint gives 3.4% higher cost than the latter. The results of this study help the container depots to plan, manage, and handle empty containers so that the container utility can be increased, and inventory costs can be minimized.