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Growing Science » Current Chemistry Letters » Synthesis and characterization of labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone and its related complexes with mercury(II) halides

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Current Chemistry Letters

ISSN 1927-730x (Online) - ISSN 1927-7296 (Print)
Quarterly Publication
Volume 3 Issue 2 pp. 103-108 , 2014

Synthesis and characterization of labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone and its related complexes with mercury(II) halides Pages 103-108 Right click to download the paper Download PDF

Authors: Alireza Dadrass, Shahla Ebrahimnezhad, Mahsa Pourmirza, Ahmad Poursattar Marjani

Keywords: Ambidentate ligand, Carbonyl stabilized phosphorus ylide, Keto ylides, Mercury(II) halide complexes, Tri-p-tolylphosphine

Abstract: The novel ?-phosphorus labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone (PTTPPY) is prepared by the reaction of 2-bromo-1-(p-tolyl)ethanone with tri-p-tolylphosphine in chloroform as solvent. The complexes of the type [HgX2(p-tolyl)3PCHCOC6H4CH3)] (X = Cl, Br and I) are prepared by the reaction of title ylide with mercury(II) halides in good yields, using methanol as solvent. The final products were characterized by IR, 1H, 13C, 31P NMR spectroscopic methods and microanalysis.

How to cite this paper
Dadrass, A., Ebrahimnezhad, S., Pourmirza, M & Marjani, A. (2014). Synthesis and characterization of labile ylide of 1-(p-tolyl)-2-(tri-p-tolylphosphoranylidene)ethanone and its related complexes with mercury(II) halides.Current Chemistry Letters, 3(2), 103-108.

Refrences
1. Wittig G. (1980) Von Diylen über Ylide zu meinem Idyll (Nobel-Vortrag), (Article first published online: 19 Jan (2006)), Angew. Chem., 92, 671-675.

2. Shen Y. (1998) New synthetic methodologies for Carbon–Carbon Double Bond Formation, Acc. Chem. Res., 31, 584-592.

3. Puke C., Erker G., Aust N.C., Wurthweine E.U., and Frohich R. (1998) Evidence for a Continuous Transition between Thiaphosphetane and Betaine-Type structures in the thio-Wittig reaction, J. Am. Chem. Soc., 120, 4863-4864.

4. Kato S., Kato T., Mizuta M., Itoh K., and lshii Y. (1973) The preparation and reactions of {[?-(trimethyl- and tripheny-l)stannyl]phenacyl}triphenylphosphonium salts and ylides, J. Organomet. Chem., 167-171.

5. Weleski E.T., Silver J., Janson M.D., and Burmeister J.L. (1975) Palladium(II), platinum(II) and mercury(II) complexes of ambidentate phosphonium, arsonium, sulfonium and pyridiniumylides, J. Organomet. Chem., 102, 365-385.

6. Uson R., Fornies J., Navarro R., Espinet P., and Mendivil C. (1985) Cationic palladium(II) complexes involving unprecedented O-coordination of acetylmethylenetriphenylphosphorane, J. Organomet. Chem., 290, 125-131.

7. Vicente J., Chicote M.T., Saura-Llamas I., Turpin J., and Fernandez-Baeza J. (1987) Keto-stabilized phosphorus ylide gold(I) and gold(III) complexes, J. Organomet. Chem., 333, 129-137.

8. Albanese J.A., Staley D.L., Rheingold A.L., and Burmeister J.L. (1990) Phosphorus ylides as hard donor Ligands, synthesis and characterization of MCl4(ylide-O)(THF) (M = Ti, Zr, Hf; ylide = (acetylmethylene) triphenylphosphorane, (benzoylmethylene)triphenylphosphorane). Molecular structure of trans ((acetylmethylene)triphenylphosphorane-O)(tetrahydrofuran)tetrachlorotitanium-(IV)-tetrahydrofuran, Inorg. Chem., 29, 2209-2213.

9. Nesmeyanov N.A., Novikov V.M., and Reutuv O.A. (1965) Properties of mercurated phosphonium salts, J. Organomet. Chem., 4, 202-210.

10. Sabounchei S.J., Nemattalab H., Salehzadeh S., Khani S., Bayat M., and Khavasi H.R. (2008) Structural, theoretical, and multinuclear NMR study of mercury(II) complexes of phosphorus ylides: Mono and binuclear complexes, Polyhedron., 27, 2015-2021.

11. Vicente J., Chicote M.T., Lagunas M.C., and Jones P.C. (1991) Synthesis and structural characterization of gold-(I), -(III) and silver(I) complexes of the ylide ligand Ph3P=CHC(O)NMe2. Crystal structure of [(AuPPh3)2{µ-C(PPh3)C(O)N-Me2}]ClO4, J. Chem. Soc. Dalton Trans., 2579-2583.

12. Onishi M., Ohama Y., Hiraki K., and Shintan H. (1982) Preparation of cationic (keto-stabilized phosphonium or sulphoniumylide)(?5-cyclopentadienyl)(triphenylphosphine)palladium(II) complexes, Polyhedron., 1, 539-540.

13. Ramirez F., and Dershowitz S. (1975) Phosphinemethylenes. II. Triphenylphosphineacylmethylenes. J. Org. Chem., 22, 41-45.

14. Sabounchei S. J., Dadrass A.R., Akhlaghi F., Nojini Z.B., and Khavasi H. (2008) Synthesis of a new carbbenzyloxymethylenetriphenylphosphorane ylide and the study of its reaction with mercury (II) halides: Spectral and structural characterization, Polyhedron., 27, 1963-1968.

15. Sabounchei S. J., Nemattalab H., Salehzadeh S., Khani S., Bayat M., and Khavasi H. (2008) Structural, theoretical and multinuclear NMR study of mercury(II) complexes of phosphorus ylides: Mono and binuclear complexes, Polyhedron., 27, 2015-2021.
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Journal: Current Chemistry Letters | Year: 2014 | Volume: 3 | Issue: 2 | Views: 3952 | Reviews: 0

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