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Growing Science » Current Chemistry Letters » Microwave synthesis, spectral, thermal, and antimicrobial activities of some transition metal complexes involving 5-bromosalicylaldehyde moiety

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Current Chemistry Letters

ISSN 1927-730x (Online) - ISSN 1927-7296 (Print)
Quarterly Publication
Volume 1 Issue 4 pp. 163-174 , 2012

Microwave synthesis, spectral, thermal, and antimicrobial activities of some transition metal complexes involving 5-bromosalicylaldehyde moiety Pages 163-174 Right click to download the paper Download PDF

Authors: Rajendra K. Jain, A. P. Mishra

DOI: 10.5267/j.ccl.2012.7.003

Keywords: 5-Bromosalicylaldehyde, Aniline, Biological activity, Microwave synthesis, Thermal analysis

Abstract: The coordination complexes of Co(II), Ni(II) and Cu(II) derived from 5-bromosalicylidene-3,4-dimethylaniline (BSMA) and 5-bromosalicylidene-3,4-dichloroaniline (BSCA) have been synthesized by conventional as well as microwave methods. These compounds have been characterized by elemental analysis, FT-IR, molar conductance, electronic spectra, 1H-NMR, FAB-mass, ESR, magnetic susceptibility, electrical conductivity and thermal analysis. The complexes are coloured and stable in air. Analytical data revealed that all the complexes exhibited 1:2 (metal: ligand) ratio with coordination number 4 or 6. IR data shows that the ligand coordinates with the metal ions in a bidentate manner through the phenolic oxygen and azomethine nitrogen. FAB-mass and thermal data show degradation pattern of the complexes. Solid state electrical conductivity studies reflect semiconducting nature of the complexes. The Schiff base and metal complexes show a good activity against the Gram-positive bacteria; Staphylococcus aureus and Gram-negative bacteria; Escherichia coli and fungi Aspergillus niger and Candida albicans.

How to cite this paper
Jain, R & Mishra, A. (2012). Microwave synthesis, spectral, thermal, and antimicrobial activities of some transition metal complexes involving 5-bromosalicylaldehyde moiety.Current Chemistry Letters, 1(4), 163-174.

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Journal: Current Chemistry Letters | Year: 2012 | Volume: 1 | Issue: 4 | Views: 3817 | Reviews: 0

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