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Growing Science » Current Chemistry Letters » Synthesis and characterization of mono- and bimetallic complexes of Zn(II) and Cu(II); new multifunctional unsymmetrical acyclic and macrocyclic phenol-based ligand

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Current Chemistry Letters

ISSN 1927-730x (Online) - ISSN 1927-7296 (Print)
Quarterly Publication
Volume 2 Issue 4 pp. 207-214 , 2013

Synthesis and characterization of mono- and bimetallic complexes of Zn(II) and Cu(II); new multifunctional unsymmetrical acyclic and macrocyclic phenol-based ligand Pages 207-214 Right click to download the paper Download PDF

Authors: Hamid Golchoubian, Maryam Rezaei

Keywords: Hetero-bimetallic complex, Pedant arm ligand, Unsymmetrical compartmental ligand Macrocyclic li, Copper displacement, Phenolate bridge

Abstract: The dicompartmental macrocyclic ligand (L2)2- was prepared by [1:1] cyclic condensation of N,N?-dimethyacetate-N,N?-ethylene-di(5-methyl-3-formyl-2-hydroxybenzylamine with 1,3-diaminopropane. The ligand includes dissimilar N(amine)2O2 and N(imine)2O2 coordination sites sharing two phenolic oxygen atoms and containing two methyl acetate pedant arms on the amine nitrogen donor atoms. A series of mono- and bimetallic complexes were synthesized and characterized on the basis of elemental analysis, molar conductance measurement, IR and UV-Vis spectroscopy techniques. It was found that during the cyclization process the copper (II) displaced from the N(amine)2O2 to the N(imine)2O2 coordination site and one of the methyl acetate pedant arms is dissociated. The heterodinuclear complex of [ZnL2Cu(?-OAc)]+ was prepared by a transmetallation reaction on the [ZnL2Zn(?-OAc)]+ by Cu(II). The characterization results showed that the two metal ions are bridged by two phenolic oxygen atoms and an acetate group, providing distorted five-coordination geometries for the both metal ions.

How to cite this paper
Golchoubian, H & Rezaei, M. (2013). Synthesis and characterization of mono- and bimetallic complexes of Zn(II) and Cu(II); new multifunctional unsymmetrical acyclic and macrocyclic phenol-based ligand.Current Chemistry Letters, 2(4), 207-214.

Refrences
1 Vigato P. A., Tamburini S. and Bertolo L. (2007). The development of compartmental macrocyclic Schiff bases and related polyamine derivatives, Coord. Chem. Rev., 251, 1311-1492.

2 Dave V. G., and Vyas P. J. (2012). Synthesis, structural elucidation and antimicrobial activities of some alkylene dithiophosphate derivatives of macrocyclic complexes of Ni (II) having N2S2 potential donors in 18 to 24 membered rings J. Curr. Chem. Pharm. Sc., 2, 133-148.

3 Golchoubian H., and Nemati Kharat A. (2005). Hydrogen peroxide oxidation of mono and disubstituted alkylarenes catalyzed by dinuclear CoIII–CuII macrocyclic complex. Polish J. Chem., 79, 825-830.

4 Murthy N. N., Mahroof-Tahir M., and Karlin K. D. (2001). Dicopper(I) complexes of unsymmetrical binucleating ligands and their dioxygen reactivities, Inorg. Chem., 40, 628-635.

5 Drewry J. A., and Gunning P. T. (2011). Recent advances in biosensory and medicinal therapeutic applications of zinc(II) and copper(II) coordination complexes, Coord. Chem. Rev., 255, 459-472.

6 Golchoubian H., Mardani H. R., Bruno G., and Rudbari H. A. (2012). Controlled synthesis of heterodinuclear complexes in dicompartmental macro-acyclic ligand with hexa- and tetra coordination sites, Polyhedron 44, 44-51.

7 Golchoubian H., Mardani H. R., Bruno G., and Rudbari H. A. (2013). Heterodinuclear Zn(II)-Cu(II) and Zn(II)-Ni(II) complexes derived from unsymmetrical phenol-based dicompartmental macro-acyclic ligands, J. Iran. Chem. Soc., 10, 29-41.

8 Golchoubian H., Fateh D. S., Bruno G., and Rudbari H. A. (2012). Dinuclear Zn(II)-M(II) (M = Zn, Cu) and Cu(II)-Cu(II) complexes derived from unsymmetrical macrocyclic ligands with double set of coordination sites. Removal of a pendant arm and migration of copper ion upon cyclization, J. Coord. Chem., 65, 1970–1991.

9 Golchoubian H., Mardani H. R., Bruno G., and Rudbari H. A. (2012). Synthesis of mono- and heterodinuclear complexes with unsymmetrical phenol-based dicompartmental ligand containing hexa- and tetradentate coordination sites: An unusual methyl elimination in coordination chemistry, Inorg. Chim. Acta, 383, 250–256.

10 Golchoubian H., Rostami L., and Kariuki B. (2010). Preparation of heterodinuclear complexes with phenol-based compartmental ligands containing hexa- and tetradentate coordination sites, Polyhedron, 29, 1525-1533.

11 Golchoubian H., Baktash E., and Welter R. (2007). Preparation and characterization of mono-and heterodinuclear complexes with dicompartmental macrocyclic ligand containing hexa- and penta coordination sites, Inorg. Chem. Commun., 10, 1035-1039.

12 Golchoubian H., Baktash E., and Welter R. (2007). Synthesis and characterization of mono- and heterodinuclear complexes with dicompartmental macrocyclic ligand containing hexa- and pentadentate coordination sites, Inorg. Chem. Commun., 10, 120-124.

13 Gavrilova A. L., and Bosnich B. (2004). Principles of mononucleating and binucleating ligand design, Chem. Rev., 104, 349-383.

14Yonemura M., Arimura K., Inoue K., Usuki N., Ohba M. and Okawa H. (2002). Coordination-position isomeric M(II)Cu(II) and Cu(II)M(II) (M = Co, Ni, Zn) complexes derived from macrocyclic compartmental ligands, Inorg Chem., 41, 582-589.

15McCollum D. G., Fraser C., Ostrander R., Rheingold A. L., and Bosnich B. (1994). Bimetallic reactivity. General synthesis of binucleating macrocyclic ligands containing 6- and 4-coordinate sites, Inorg. Chem., 33, 2383-2392.

16 Fraser C., Ostrander R., Rheingold A. L., White C., and Bosnich B. (1994). Bimetallic reactivity. controlled synthesis of monometallic and homo- and heterobimetallic complexes of a chiral binucleating macrocyclic ligand bearing 6- and 4-coordinate sites, Inorg. Chem., 33, 324-337.

17 Hansen P.W., and Jensen P.W. (1994). Vibrational studies on bis-terpyridine-ruthenium(II) complexes, Spectrochim. Acta, 50, 169-183.

18 Robinson W. (1991) Practical Handbook of Spectroscopy, 481 CRC Press, Boca Raton, Finland.
19 Silverstein R. M., and Bassler G. C. (1991) Spectrometric Identification of Organic Compounds, John Wiley & Sons, New York.

20 Deacon G. B., and Phillips R. J. (1980). Relationships between the carbon-oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination, Coord. Chem. Rev., 33, 227-250.

21Golchoubian H., and Waltz W. L. (1998). A simple and convenient method for syntheses of phenolic amino aldehyde ligands, enalH(2) and tnalH(2), Synth. Commun., 28, 3907-3912.

22 Geary, W.J. (1971). The use of conductivity measurements in organic solvents for the characterization of coordination compounds, Coord. Chem. Rev., 7, 81-122

23 Golchoubian H., and Mardani H. R. (2010). A convenient and efficient one step method for synthesis of dicompartmental ligands with hexa- and tetradentate coordination sites , Bull. Chem. Soc. Ethiopia, 24, 151-155.

24 Fraser C. Johnston L. Rheingold A. L. Haggerty B. S. Williams G. K. Whelan J. and Bosnich B., (1992). Bimetallic reactivity. Synthesis, structure, and reactivity of homo- and heterobimetallic complexes of a binucleating macrocyclic ligand containing 6- and 4-coordination sites, Inorg. Chem., 31, 1835-1844.
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Journal: Current Chemistry Letters | Year: 2013 | Volume: 2 | Issue: 4 | Views: 3254 | Reviews: 0

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