This study aims to evaluate the impact of transparency of budget structure on risk of getting into financial distress in Vietnam. The article uses data regarding equity proportion from the financial r... reports of business entities on Hanoi Stock Exchange (HNX), divided into four main categories, namely large ownership, institutional ownership, managerial ownership, and state ownership ratio, to find the relation between the allocation of equity and the chance a company having financial failure. From the mentioned information, the research attempts to explain the relations, as well as suggestions for companies to prepare and avoid financial distress from an equity structure perspective. Results from the study’s sample show insignificant correlations between the share of owners and financial distress situation of a company, which plays a part to help the overall estimation of risk in businesses as a whole  more

The corrosion inhibition power of an eco-friendly green inhibitor Ixora coccinea extract (ICE) for mild steel in 1 M HCl and 0.5 M H2SO₄ was analysed using physicochemical and electr... rochemical techniques. 1–5 v/v% ICE was prepared and added into the corrosive acidic media for different analyses. Weight loss measurements conducted for a period of 24hrs for mild steel immersion revealed 89.38% and 77.96% inhibition capacity of ICE in 1 M HCl and 0.5 M H2SO₄ medium respectively. Electrochemical impedance parameters show that as concentration is increased, efficiency increases and double layer capacitance decreases. Potentiodynamic polarization techniques are also in good agreement with impedance studies and exhibit the mixed type inhibition character of ICE. Electrochemical noise spectrum also strongly supports the anti-corrosive property of ICE and the magnitude of noise signal decreases concerning the increase in ICE concentration. Ixorene, which is one of the major constituents of Ixora coccinea leaves was also studied for its corrosion inhibition nature by quantum mechanical calculations and was found to match with all other results. Adsorption studies of ICE are in accordance with Langmuir isotherm. Surface morphological studies confirm the formation of a protective barrier on mild steel surface in both media, i.e., 1 M HCl and 0.5 M H2SO₄  more

In a short runtime process (about 6 minutes), with isocratic method without need of reconditioning before the next run, a mixture of some molecules containing 4-aminophenol (4APh), phenol, 3-nitrosali... icylic acid (3NSA), and mesalamine (5-aminosalicylic acid) (MLZ), were separated and detected by means of HPLC/UV-Vis system. The resolutions of the separated and sharp peaks referring to the mentioned compounds were at least more than 2, and the tailing factor (TF) was about 1, even in 1 µg/l (ppm) concentration. In order to optimize the method, the effects of the pH, eluent percentage, flow rate, and buffer concentration, and wavelength on the chromatogram were investigated. Also, the results of the validation processes showed that the method trustable to be used in laboratories.
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In line with Sharia principles, this study explores the correlation between increased returns and heightened risks, aligned with Al-Ghunm bi Al-Ghurm. Daily data from the Jakarta Islamic Index 70, spa... anning December 2021 to November 2023, was analysed using quantitative methods. Four key trading strategies were assessed: buy-and-hold and three Ichimoku strategies (Conservative, Moderate, and Aggressive). The results indicate the effectiveness of a moderate Ichimoku strategy because of its well-balanced approach. Despite no significant performance differences between Ichimoku's trading rules and buy-and-hold, the study emphasizes nuanced decision-making for diverse investor preferences. The insights benefited Indonesian Sharia investors, suggesting enhancements in risk mitigation techniques, and considering external factors. Enriching technical analysis and Sharia-compliant investments, this study underscores the importance of aligning financial objectives with ethical considerations, contributing to the evolving landscape of the Indonesian Sharia stock market  more

Curcumin loading capacity of polyethylene glycol (PEG) functionalized graphene and graphene oxides are investigated using molecular dynamics and Monte Carlo (MC) adsorption locator simulations. These ...  simulation methods were performed as a function of oxidation extent to study the effect of functional groups on curcumin loading and release properties. Adsorption locator energy calculations suggest that the curcumin drug molecule prefers to adsorb at the less oxidized sites of graphene oxide. One of the phenolic rings of curcumin drug prefers to have a planar interaction with graphene and graphene oxide framework due to the pi-pi interaction. Molecular dynamic studies are conducted in aqueous medium under neutral pH. Mean square displacement and radial distribution functions are obtained to determine the nature of the curcumin attachment and release in aqueous medium. The molecular simulations show that separation distance of the curcumin molecule from GO sheet is 4.4 Å. The molecular simulations presented in this work will help to design new synthetic methods of nanocarriers for curcumin delivery applications  more

One-pot synthesis of highly substituted pyridines has been demonstrated via multicomponent reaction of aldehydes, malononitrile and thiophenol using Mg-Al hydrotalcite as a solid base and reusable cat... talyst. The catalytic activity is intimately connected to the basicity of the catalyst. The best activities were observed with the Mg/Al: 5 catalyst. The catalyst could be reused for further run without a significant loss in activity. The protocol was also applicable for various aromatic aldehydes which affords desired product in good to excellent yield  more

This study was focused to investigate the adsorptive behavior of activated carbon prepared from wheat straw treated with acid and base for the removal of 2, 4-dichlorophenoxy acetic acid (2,4-D). The ...  morphology of the adsorbent was characterized using infrared spectroscopy and scanning electron microscopy. Compared with acid activated wheat straw, base activated wheat straw has provided lower ash content, moisture and volatile matter. However, it has higher iodine number than acid activated wheat straw. The removal of 2,4-D from aqueous solution was investigated at various physicochemical parameters such as pH (2–10), contact time (5–60 min), temperature (20-80 oC), amount of adsorbent (0.1-1.4 g) and initial concentration of 2,4-D (1.0-25 mg/L). The removal efficiency of 2,4-D in aqueous solution was found to be 92.02%. The equilibrium data were analyzed using Langmuir and Freundlich isotherm and the Langmuir model better describes that the active adsorption sites were homogeneously distributed on the surface of the adsorbent. Therefore, the activated carbon prepared from wheat straw treated with base can be used as efficient and cost-effective method to remove 2,4-D from aqueous solution  more

A simple and efficient method for the synthesis of fifteen novel ketene dithioacetals (2-(6-amino5-cyano-4-aryl-4H-1,3-dithiin-2-ylidene) malononitrile) via a one-pot three-component rea... action of activated methylene group malononitrile with carbon disulfide in the presence of arylidene malononitriles were reported. The effects of LiOH.H₂O as a base at different concentrations have been investigated and can provide products in good yields at 40-50ºC temperature (54-89%). All the synthesized ketene dithioacetals compounds (MCB1-MCB15) were checked for favorable pharmacokinetic param¬eters along with toxicities which are based on drug-likeness explained by Lipinski’s rule of five by Med chem designer software correlated with that of pkCSM online tool. Explorations of synthesized ketene dithioacetals compounds for the antimicrobial study were found to be effective towards Staphylococcus aureus (MCB5 and MCB13) with a zone of inhibition at 26mm and 22mm which is compared to that of standard ciprofloxacin (26mm). This made our study to explore the inhibition mechanism with the help of molecular docking studies with possible binding energies (-6.4 to -8.9 kJ/mol) by pyrx 0.8 software to represent a good prediction of interactions between the ligand and protein (2XCT). Further evaluation of druggability and ADMET predictions compounds MCB5 and MCB13 were found to be effective. Based on the in-vitro and in-silico studies a series of ketene dithioacetals compounds may be helpful for further studying SAR and designing more potent antimicrobials  more

This study reports the flow stress behavior of three P92 steels with different compositions. Uniaxial compression tests were conducted in the deformation temperature range of 575 °C to 650 °C and stra... ain rate range of 0.001-0.5 s-1 using a Gleeble® 3500 thermo-mechanical simulator. A simple physically-based constitutive model was used to analyse the effects of deformation conditions (temperature and strain rate) on the metal flow stress behavior during the deformation process. The method accounts for the temperature dependence of Young’s modulus and the lattice self-diffusion coefficient of Fe in the ferrite. Constitutive equations describing the flow stress behavior of the three P92 steels were developed. From the results, the stress exponent n of 26.13(steel A), 21.61(steel B) and 27.55 (steel C) were obtained using the self-diffusion activation energy in the physically-based constitutive equation. From the results, the three steels had variation in the stress exponent values, which was attributed to differences in elemental content, such as chromium and tungsten. The developed constitutive equations were verified using statistical parameters: Pearson’s correlation coefficient (R) and average absolute relative errors (AARE). Statistical analysis showed that the three steels had the same R of 0.98, while AARE was: 1.68 (steel A), 1.72 (steel B), and 1.82 (steel C). The constitutive equations developed showed a good correlation between the experimental and predicted flow stress data. Hence, the method is applicable in describing flow stress behavior in the metalworking process in the industry  more

Designing an efficient supply chain for organ transplant networks which is intimately related to humans’ life plays a primary role in improving the network’s performance. This research is focused on p... proposing a new multi-period location-allocation modeling approach to make appropriate strategic decisions for designing organ transplant networks under supply and budget uncertainties. To serve this purpose, a bi-objective possibilistic programming model is formulated the aim of which is to maximize network responsiveness and minimize the total cost. A fuzzy goal programming approach is adopted to solve multiple objective function models and control their deviations from the corresponding aspiration levels. As an important contribution of this study, the chance of success of transplantation processes is taken into consideration by proposing appropriate utility functions according to transportation criteria. Moreover, for the purpose of coping with the inherent uncertainty of the input parameters, a possibilistic programming model based on Me measure converted to three optimistic, realistic and pessimistic models is developed. Three new formulations have also been developed to tackle equality chance constraints. Finally, the optimal solutions of the developed models are analyzed through conducting a real case study in Iran. According to the results, for the considered organ transplant network, the possibilistic programming model based on the realistic measure is better than the optimistic and pessimistic measure in most confidence levels  more