Kinetic studies were made of the reactions between triphenylphosphine 1 and dialkyl acetylenedicarboxylates 2, in the presence of NH-acids, such as benzotriazole, 5-methylbenzotriazole or 5-chlorobenzotriazole 3 (as a protic/nucleophilic reagent). To determine the kinetic parameters of the reactions, they were monitored by UV spectrophotometry. Useful information was obtained from studies of the effect of solvent, structure of reactants (dialkyl acetylenedicarboxylates and NH-acids) and also concentration of reactants on the reaction rates. First and third steps (k2, k3) of all reactions were recognized as a rate determining and fast steps, respectively. Proposed mechanism was confirmed on the basis of experimental data.

Radio-frequency identification (RFID) is the wireless non-contact implementation of radio-frequency electromagnetic fields to transfer necessary data to identify and to track tags attached to objects, automatically. RFID has been successfully used for supply chain management (SCM) problems in order to reduce errors associated with inventory. This paper uses RFID technique in five different scenarios of labeling, errors in stolen parts, waste, wrong replacement and delivery. The study uses simulation technique based on Enterprise Dynamics to analyze three parts in an auto industry. The study considers different criteria including inventory error estimation, profitability, profitability, customer satisfaction and SCM performance. The preliminary results indicate that the proposed method is capable of optimizing most objectives, significantly.

Composite materials due to high strength and stiffness to their weight ratio are widely used in different structures. Hence, it is necessary to predict their failure behavior under loading. The delamination due to interlaminar stresses at free edges is one of the most important damage modes in laminated composites. In this study, this mode in cross-ply and angle-ply laminates has been investigated using a cohesive zone model. The advantage of this method is the possibility of modeling the delamination initiation and propagation without requirement to the presence of initial crack and remeshing. Hence, at first an interface element based on bilinear cohesive law was implemented in Ansys. Next, laminated plates with different lay-ups under uniaxial tension loading were modeled. Also Hashin’s failure criteria were used to predict ply damage initiation. Numerical results show that in angle-ply laminates with small fiber angle orientation, delamination in the shear mode is the dominant mode in the loss of structural strength. The numerical and experimental results for global load-displacement response show a good agreement. Also numerical results show that in cross-ply laminates even under in-plane loading, the damage behavior extremely depends on the stacking sequence. Studies show that in cross-ply laminates under uniaxial tension, if 90o plies are inserted in top and bottom surface of the laminate, the mode I delamination and matrix cracking will start later.

This paper presents an investigation on the role of packaging design on persuading consumer to buy different products in city of Tehran, Iran. The proposed study designs a questionnaire in Likert scale consists of 26 questions, distributes it among some Iranian experts and analyzes it based on principal component analysis. During the survey, the number of questions is reduced from 26to 23. Cronbach alpha is calculated as 0.88 and Kaiser-Meyer-Olkin Measure of Sampling Adequacy and Approx. Chi-Square are 0.80 and 1880, respectively. Based on the results of our survey, we have derived five factors including requirement attributes, proportionality components, consumer choice, product appearance attractiveness and consumer characteristics.

Efficient synthesis of quinoxaline derivatives from the reaction of ?-diketones and o-phenylenediamines in the presence of Keggin-type heteropolyacids (HPA) such as H3PMo12O40, H4SiW12O40, K7PMo2W9O40, H3PW12O40.SiO2 and H3PW12O40 in high yields and short reaction times, and at room temperature is introduced.

One of the methods to reach continuous improvement on economy is to boost export and target international market. However, there are some limits on available resources, which present most developing countries for improvement of export activities. One way to overcome such trouble is to use foreign direct investment but this may happen only when we could determine major barriers and overcome the challenges. The present study presents an empirical investigation to detect important barriers on foreign direct investment in Iranian industries. The proposed study uses structural equation modeling to detect major barriers for export development. The results of our survey indicate that there were four factors including economic factors, feasibility study, infrastructure for investment and investment resources influencing on foreign direct investment.

In this paper, harmonic forced vibration of circular functionally graded plate integrated with two uniformly distributed actuator faces made of piezoelectric material is studied. The material properties of the functionally graded substrate layers are assumed to be graded in the thickness direction according to the power-law distribution, also the distribution of electric potential field along the thickness direction of piezoelectric layers is modeled by a quadratic function. The governing equations are solved for simply supported boundary condition of the sandwich circular plate and the solutions are presented by elementary Bessel functions. The performance of the present model is compared with that of ?nite element analyses as well as other available literature by the presentation of comparative results obtained for several examples encompassing different power indexes and vibration modes. The results show that thickness of piezoelectric layer and changing the power index in FG material has a significant influence on the deflection and natural frequencies of system.

Cold working a hole decreases tendency of fatigue crack initiation and growth near the hole. It is due to creation of some compressive tangential residual stresses around the hole. But there are many uncertainties which affect the residual strain and residual stress field. In fact these uncertainties lead to have scatter in the test results and considering the residual strains and residual stresses as random variables. In this paper strains recorded by strain gages mounted around the hole during cold working process in seven pieces specimens, were analyzed by statistical tests and stochastic properties of mentioned random variables were obtained using SPSS software. The residual strains have been also distributed by normal probability distribution function.

In this paper, a multi products single machine economic production quantity model with
discrete delivery is developed. A unique cycle length is considered for all produced items with
an assumption that all products are manufactured on a single machine with a limited capacity.
The proposed model considers different items such as production, setup, holding, and
transportation costs. The resulted model is formulated as a mixed integer nonlinear
programming model. Harmony search algorithm, extended cutting plane and particle swarm
optimization methods are used to solve the proposed model. Two numerical examples are used
to analyze and to evaluate the performance of the proposed model.

Portfolio selection is one of the important problems encountered by any investor. The purpose of this paper is to solve a real stock portfolio selection problem in Iran. According to the uncertain environments in which financial decisions are made, most of the recent works in this field use fuzzy sets theory in order to incorporate these uncertainties into their analysis. The problem is to determine how to allocate a limited fund among the stocks of some pharmaceutical companies in Tehran stock exchange. For this purpose we apply two fuzzy analytic hierarchy process (FAHP) methods to this problem. Finally, the results obtained from the two methods are compared in terms of the solution quality.