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Growing Science » Current Chemistry Letters » Synthesis and Characterization of Some Derivatives of 1,3-Diisopropyl-4,5-dimethylimidazol-2-ylidene

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Current Chemistry Letters
ISSN 1927-730x (Online) - ISSN 1927-7296 (Print)
Quarterly Publication
Volume 9 Issue 4 pp. 199-204, 2020

Synthesis and Characterization of Some Derivatives of 1,3-Diisopropyl-4,5-dimethylimidazol-2-ylidene Pages 199-204 Right click to download the paper Download PDF

Authors: Eyad Mallah, Kamal Sweidan, Luay Abu-Qatouseha, Tawfiq Arafat, Rajendra Joshi

📋 Author Affiliations:
E. Mallah1, K. Sweidan2, L. Abu-Qatouseha1, T. Arafat3, R. Joshi4
1 Faculty of Pharmacy and Medical Sciences, University of Petra, Amman, Jordan
2 Department of Chemistry, The University of Jordan, Amman, Jordan
3 Jordan Center for Pharmaceutical Research, Amman, Jordan
4 Department of Chemical Science and Engineering, School of Engineering, Kathmandu University, Nepal
doi 10.5267/j.ccl.2020.4.001
Crossref 1 Source: CrossRef

🔑 Keywords:

Abstract: N-Heterocyclic carbenes are widely used in organic reactions and coordination chemistry. In the present study, 2,3-dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene (1) is reacted with diphenyl disulfide, methyl phenyl disulfide, and bis(methylsulfonyl)methane to yield target compounds 5, 6, and 7 respectively. Structures of these compounds are well established using nuclear magnetic resonance, mass spectrometry and elemental analysis. Possible reaction mechanisms are proposed.


How to cite this paper
APA: Mallah, E., Sweidan, K., Abu-Qatouseha, L., Arafat, T & Joshi, R. (2020). Synthesis and Characterization of Some Derivatives of 1,3-Diisopropyl-4,5-dimethylimidazol-2-ylidene. Current Chemistry Letters, 9(4), 199-204.
Chicago/Turabian: Mallah, E., Sweidan, K., Abu-Qatouseha, L., Arafat, T & Joshi, R. 2020. "Synthesis and Characterization of Some Derivatives of 1,3-Diisopropyl-4,5-dimethylimidazol-2-ylidene." Current Chemistry Letters 9, no. 4 (2020): 199-204.
AMA: Mallah, E., Sweidan, K., Abu-Qatouseha, L., Arafat, T & Joshi, R. Synthesis and Characterization of Some Derivatives of 1,3-Diisopropyl-4,5-dimethylimidazol-2-ylidene. Current Chemistry Letters. 2020;9(4):199-204.

References

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6. Kuhn, N., Steimann, M. and Sweidan, K. (2005) The crystal structure of 1, 3-dicyclohexyl-4, 5-dimethylimidazolium dicyanomethylide. Z. Naturforsch. B 1(1), 123-124.
7. Kuhn, N., Abu-Rayyan, A., Al-Sheikh, A., Eichele, K., Maichle-Moßmer, C., Steimann, M. and Sweidan, K. (2005) The structural chemistry of 2-methylenimidazolines (In German). Z. Naturforsch., 1(3), 294-299.
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12. Talavera, G., Pena, J., and Alcarazo, M. (2015) Dihalo (imidazolium) sulfuranes: A versatile platform for the synthesis of new electrophilic group-transfer reagents. J. Am. Chem. Soc., 137 (27), 8704-8707.
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14. Dayyih, W. A., Mallah, E., Sweidan, K., Al-Sheikh, A., and Steimann, M. (2013) Crystal structure of 1, 3-diisopropyl-4, 5-dimethylimidazolium oxalic acid monomethyl ester, C14H24N2O4. Z. Krist.-New Cryst. St., 228 (1), 55-56.
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📚 Journal: Current Chemistry Letters | 📅 Year: 2020 | 📖 Volume: 9 | 📄 Issue: 4 | 👁️ Views: 1416 | 📊 Crossref: 1

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