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Growing Science » Current Chemistry Letters » Synthesis of allyl-glycidyl ether by the epoxidation of diallyl ether with t-butyl hydroperoxide over the Ti-MWW catalyst

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Current Chemistry Letters

ISSN 1927-730x (Online) - ISSN 1927-7296 (Print)
Quarterly Publication
Volume 6 Issue 1 pp. 7-14 , 2017

Synthesis of allyl-glycidyl ether by the epoxidation of diallyl ether with t-butyl hydroperoxide over the Ti-MWW catalyst Pages 7-14 Right click to download the paper Download PDF

Authors: Agnieszka Wróblewska, Marika Walasek, Beata Michalkiewicz

DOI: 10.5267/j.ccl.2016.11.002

Keywords: Diallyl ether, Allyl-glycidyl ether, Ti-MWW, t-Butyl hydroperoxide, Epoxidation

Abstract: In this paper, modified hydrothermal method for Ti-MWW catalyst preparation has been shown. Instrumental analysis of the zeolite material Ti-MWW has been performed by means of UV-vis spectrometry, infrared spectrometry (IR), scanning electron microscope (SEM), X-ray diffraction (XRD), and X-ray microanalysis. Moreover, the results of the epoxidation of diallyl ether (DAE) over the titanium silicate catalyst Ti-MWW and in the presence of methanol have been presented. t-Butyl hydroperoxide have been applied for the first time as an oxidant for this process. The influence of temperature (20-130°C), DAE/TBHP molar ratio (1:1-3:1), methanol concentration (10-80 wt%), amount of catalyst (1-7 wt%) and reaction time (60-1440 min.) was studied. The main functions describing the process were determined on the basis of the results obtained from the gas chromatography method.

How to cite this paper
Wróblewska, A., Walasek, M & Michalkiewicz, B. (2017). Synthesis of allyl-glycidyl ether by the epoxidation of diallyl ether with t-butyl hydroperoxide over the Ti-MWW catalyst.Current Chemistry Letters, 6(1), 7-14.

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Journal: Current Chemistry Letters | Year: 2017 | Volume: 6 | Issue: 1 | Views: 2943 | Reviews: 0

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