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{journals}

Current Chemistry Letters

ISSN 1927-730x (Online) - ISSN 1927-7296 (Print)
Quarterly Publication
Volume 4 Issue 2 pp. 55-60 , 2015

The synthesis of polystyrene with a new chemical approach Pages 55-60 Right click to download the paper Download PDF

Authors: Naima Bensaada, Moulkheir Ayat, Rachid Meghabar, Mohammed Belbachir

doi 10.5267/j.ccl.2015.3.002
Crossmark

Keywords: Montmorillonite, Polymerization, Polystyrene

Abstract: The bulk room-temperature polymerization of styrene initiated by environmentally friendly catalysts Maghnite-Na+ is investigated. The catalyst removed from the reaction mixture simply by filtration could be regenerated and reused. The effect of the Maghnite-Na+ catalyst loading on degree of polymerization had been studied and state their inverse relation. The catalyst was characterized by X-ray diffraction and FTIR spectroscopy.

How to cite this paper

Bensaada, N., Ayat, M., Meghabar, R & Belbachir, M. (2015). The synthesis of polystyrene with a new chemical approach.Current Chemistry Letters, 4(2), 55-60.

References
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4. Ma H., Wan X., Chen X., Zhou Q.F. (2003) Reverse Atom Transfer Radical Polymerization of Methyl Methacrylate in Room-Temperature Inoic Liquids. J. Polym. Sci., part A: Polym. Chem., 41, 143-151.

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6. Vijayaraghavan R., Pringle J.M., MacFarlane D.R. (2008) Anionic polymerization of styrene in ionic liquids. Eur. Polym. J., 44, 1758-1762.

7. Marechal J.M., Carlotti S., Shcheglova L., Deffieux A. (2003) Stereoregulation in the anionic polymerization of styrene initiated by superbases. Polymer, 44, 7601-7607.

8. Carlotti S., Desbois P., Warzelhan V., Deffieux A. (2009) Retarded anionic polymerization (RAP) of styrene and dienes. Polymer, 50, 3057-3067.

9. Carlotti S., Menoret S., Barabanova A., Desbois P., Deffieux A. (2007) Sodium hydride as a new initiator for the retarded anionic polymerization (RAP) of styrene. Polymer, 48, 4322-4327.

10. Belbachir M., Bensaoula A. (2001) Composition and method for catalysis using bentonites. US Patent 6, 274, 527, B1.

11. Ferrahi M.I., Belbachir M. (2007) Cyclic polyesters prepared by poly(oxypropylene oxymaloyl) ring-chain reactions. eXPRESS Polym. Letters, 1, 24-26.

12. Rieger J. (1996) The glass transition temperature of polystyrene. J. Therm. Anal., 46, 965-972.

13. Amr, I. T., Al-Amer, A., Al-Harthi, M., Girei, S. A., Sougrat, R., Atieh, M. A. (2011) Effect of acid treated carbon nanotubes on mechanical, rheological and thermal properties of polystyrene nanocomposites. Composites: Part B, 42, 1554-1561.
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Journal: Current Chemistry Letters | Year: 2015 | Volume: 4 | Issue: 2 | Views: 2875 | Reviews: 0

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