Batch adsorption and desorption kinetic experiments of fenitrothion on clay soil and sandy clay loam soil indicated that the equilibration time was approximately 30 hours. The kinetics of adsorption and desorption exhibited two distinct stages: a rapid process in the initial stages followed by a slow process. The pseudo-first-order model followed by the Elovich kinetic model fit the experimental adsorption and desorption data quite well, with high values of R2 and low values of ∆qe% and SSE. Accordingly, the pseudo-first-order model is most suitable for describing the adsorption and desorption kinetics of fenitrothion on clay soil and sandy clay soil. Pseudo-second-order model type-1 and type-2 models fit the experimental adsorption data; however, these models cannot be used to describe desorption kinetics. Moreover, the modified Freundlich model has limited applicability, and the intraparticle diffusion kinetic model cannot describe the kinetics of the adsorption and desorption of fenitrothion on clay and sandy clay loam soils.

Multi-purpose forest fire fighting vehicles should carry a set of firefighting equipment such as high-pressure water pumps, tree cutters to create a fire isolation corridor, vacuum, and blowing machine high-speed wind sandblasting devices etc. The bumpy road and velocity of moving vehicles can affect the vibration response of these vehicles. Hence, in this research the vibration analysis of a Multi-purpose forest fire fighting vehicle mounted on a URAL4320 active three-wheel drive vehicle is simulated and analyzed. The effect of road bumping and speed of vehicle on the vibration parameters are studied via building mathematical models with 19 degree of freedom for simulating the suspension system of the investigated vehicle.