A series of furan derivatives tebufenozide analogues comprising five compounds (2, 3, 4, 5, and 6) have been designed and synthesized via reaction of N'-phenylfuran-2-carbohydrazide (1) with different acid chlorides. The structures of the synthesized compounds were identified by elemental analyses and spectroscopic data. The analogues compounds have the active center of tebufenozide (mimic) with change of tertiary butylhydrazine by phenylhydrazine. Studying the effect of this change on the toxicological activity against Spodoptera littoralis larvae was performed for three compounds of the synthesized ones. Toxicological activity data showed that compound (3) is more active than compounds (2) and (5)

Mesoporous materials are substances whose pores maintain diameters between 2 and 50 nm, according to IUPAC nomenclature. This paper presents a comprehensive scientometrics on the existing trend on mesoporous materials in chemistry. The study uses Web of Science database as the primary source of value added articles and performs different methods for detecting highly cited articles, most active countries, etc. The search of articles using Web of Science was accomplished with two keywords “Mesoporous materials” and “Chemistry”. In Web of Science, there were about 800 articles related to these keywords over the period 1900-2019. Then the articles were arranged according to the citation order in non-increasing order, and among them, we found about 200 highly cited articles. According to our survey, green chemistry, water, heterogeneous catalysis and aqueous-solution build a structure on mesoporous materials. Moreover, conversion, guest molecules, triblock, oxidation, heterogeneous catalysts set the corner of other structure of the study. The survey also indicates that there were three clusters associated with mesoporous materials in chemistry. In the first cluster silica appears to be the most important word followed by molecularsieves and MCM-41. Organic-group is the most important word in the second cluster followed by hybrid materials. In cluster 3, nanoparticles appears to be the most important word followed by functionalization. In our study, absorption, nanoparticles and drug-delivery are detected as the emerging keywords and future studies could be concentrated on these subjects.

Metal–organic frameworks (MOFs) are combinations of metal ions or clusters accommodated to organic ligands to shape different dimensional structures. MOFs are considered as a subclass of coordination polymers, with the possible characteristics that they are normally porous. The metals are considered to offer flexible, co-ordination environment under virtually various topologies. Besides, because of the usual liability of metal complexes, the shape of the coordination bonds between the metal ions and the organic linkers can be reversible and this helps the rearrangement of metal ions and organic linkers through the process of polymerization to give highly ordered framework structures. The study has indicated that MOFs has maintained extensive applications in Biological imaging and sensing, Drug delivery systems, Methane storage, Semiconductors, Bio-mimetic mineralization, Carbon capture, Desalination/ion separation, Water vapor capture and Ferroelectrics and Multiferroics. This paper presents a scientometrics study on 1273 papers published articles, books, patents, etc. indexed in Web of Science database over the period 2001-2019. The study presents the most popular keywords used in the literature, determines the network of scientific scholars and discusses the clusters of keywords used for different surveys. The results indicate that metalorganic frameworks and zeoitic imidazolate frameworks are two keywords considered as motor keywords in MOFs studies.