Safety risk and operational efficiency in sustainable coal supply was an issue in the coal distribution supply chain. An online survey evaluating safety hazards, operational effectiveness, logistic service providers, and sustainable supply chain management was completed by 89 consumers of coal logistic service providers. In contrast, this study aimed to evaluate the operational effectiveness and safety concerns of a sustainable coal supply chain managed by the logistic service providers on the Barito River. In addition to using path analysis, quantitative research methods were also applied to calculate and process the questionnaire data, producing a value that determined the weight of each vendor, criterion, and sub-criterion. It showed several positive and significant influences connected to the safety of sustainable supply chain management, the operational efficiency of logistic service providers, supply chain management, and security risks for the providers. Therefore, it was essential to unite the positive influences on the logistic flow to secure the coal supply chain activities on the Barito River. This research would have theoretical and practical applications, adding to the advancement of science through its applications. Such knowledge would affect the safety risk and operational efficiency of sustainable supply chain management through the logistic service providers on the Barito River, Central Kalimantan.