The article is devoted to some aspects of research of hostile environment influence on the concrete durability. The mechanism of formation of chaotically diversified difficult structure is described. Chemical interactions of cement with active components of diffusion in steam space are examined. Measures for receiving conditions under which the volume of products of reaction will be equal to the volume of the reacted alkaline components of a cement stone are offered. High-quality and quantitative changes in a pore space, which are irrespective of density and the relative molecular mass of reaction products are described. Besides, movement and distribution of gaseous products of reaction in volumes of a cement stone are simulated. Reasonable integrated dependences of influence of aggressive environment on various types of concrete surfaces are given. The methods of corrosion control offered in article allow substantially to lower or absolutely to exclude adverse effect of hostile environment on concrete and reinforced concrete structures already at a stage of selection of composition of concrete mix. In this case service life of concrete and reinforced concrete structures will increase.