Processing, Please wait...

  • Publisher Home
  • Home
  • 🔙 Back
  • 📚 Journals
    • ⚙️ IJIEC - Industrial Engineering Computations
    • 🌐 IJDNS - Data and Network Science
    • 🧪 CCL - Current Chemistry Letters
    • 💹 AC - Accounting
    • 🎯 DSL - Decision Science Letters
    • 🚛 USCM - Uncertain Supply Chain Management
    • 🏗️ JPM - Journal of Project Management
    • 🏥 HE - Healthcare Engineering
    • 📈 SCI - Scientometrica
    • 🔩 ESM - Engineering Solid Mechanics
    • 🌿 JFS - Journal of Future Sustainability
    • 💼 MSL - Management Science Letters
  • 📝 Submit Article
  • 📊 Statistics
  • 📋 About
    • 📄 About Us
    • 📰 Blog
    • 📢 News
    • 📧 Contact
  • 📺 Tutorial
  • Search:
  • Advanced Search

Growing Science » Engineering Solid Mechanics » Fly ash utilization as support of nano zinc oxide composite catalyst for methanolysis of kapok (Ceiba Pentandra) seed oil

⭐ Highly Cited Articles

  • Jaya Algorithm
  • Rao Algorithm
  • TLBO Algorithm
  • ChatGPT and Blended Learning

Journals

  • IJIEC (840)
  • IJDS (1032)
  • DSL (759)
  • ESM (434)
  • CCL (563)
  • JPM (350)
  • AC (572)
  • JFS (106)
  • MSL (2658)
  • USCM (1104)
  • HE (54)
  • SCI (52)

ESM Volumes

    • ▼ Volume 14 (30)
      • Issue 1 (9)
      • Issue 2 (8)
      • Issue 3 (7)
      • Issue 4 (6)
    • ▼ Volume 13 (32)
      • Issue 1 (12)
      • Issue 2 (7)
      • Issue 3 (7)
      • Issue 4 (6)
    • ▼ Volume 12 (41)
      • Issue 1 (10)
      • Issue 2 (9)
      • Issue 3 (12)
      • Issue 4 (10)
    • ▼ Volume 11 (39)
      • Issue 1 (10)
      • Issue 2 (10)
      • Issue 3 (9)
      • Issue 4 (10)
    • ▼ Volume 10 (35)
      • Issue 1 (9)
      • Issue 2 (8)
      • Issue 3 (10)
      • Issue 4 (8)
    • ▼ Volume 9 (36)
      • Issue 1 (9)
      • Issue 2 (9)
      • Issue 3 (9)
      • Issue 4 (9)
    • ▼ Volume 8 (36)
      • Issue 1 (8)
      • Issue 2 (10)
      • Issue 3 (9)
      • Issue 4 (9)
    • ▼ Volume 7 (28)
      • Issue 1 (7)
      • Issue 2 (6)
      • Issue 3 (7)
      • Issue 4 (8)
    • ▼ Volume 6 (32)
      • Issue 1 (8)
      • Issue 2 (8)
      • Issue 3 (8)
      • Issue 4 (8)
    • ▼ Volume 5 (25)
      • Issue 1 (7)
      • Issue 2 (6)
      • Issue 3 (6)
      • Issue 4 (6)
    • ▼ Volume 4 (25)
      • Issue 1 (5)
      • Issue 2 (7)
      • Issue 3 (7)
      • Issue 4 (6)
    • ▼ Volume 3 (27)
      • Issue 1 (7)
      • Issue 2 (7)
      • Issue 3 (6)
      • Issue 4 (7)
    • ▼ Volume 2 (32)
      • Issue 1 (6)
      • Issue 2 (8)
      • Issue 3 (10)
      • Issue 4 (8)
    • ▼ Volume 1 (16)
      • Issue 1 (4)
      • Issue 2 (4)
      • Issue 3 (4)
      • Issue 4 (4)

🔑 Keywords

Jordan(175)
Supply chain management(172)
Vietnam(154)
Customer satisfaction(124)
Performance(117)
Supply chain(115)
Artificial intelligence(108)
Service quality(101)
Competitive advantage(100)
SMEs(95)
Sustainability(94)
Tehran Stock Exchange(94)
optimization(88)
Financial performance(86)
TOPSIS(85)
Trust(85)
Genetic Algorithm(81)
Organizational performance(81)
Job satisfaction(81)
Social media(80)


» Show all keywords

✍️ Authors

Naser Azad(82)
Zeplin Jiwa Husada Tarigan(70)
Mohammad Reza Iravani(65)
Endri Endri(45)
Hotlan Siagian(43)
Muhammad Alshurideh(42)
Dmaithan Almajali(39)
Jumadil Saputra(37)
Muhammad Turki Alshurideh(35)
Ahmad Makui(33)
Sautma Ronni Basana(33)
Barween Al Kurdi(32)
Basrowi Basrowi(31)
Mohammad Khodaei Valahzaghard(30)
Haitham M. Alzoubi(30)
Ni Nyoman Kerti Yasa(30)
Hassan Ghodrati(30)
Shankar Chakraborty(29)
Sulieman Ibraheem Shelash Al-Hawary(28)
Mahmoud Allahham(28)


» Show all authors

🌍 Countries

1. Algeria (52)
2. Angola (2)
3. Argentina (22)
4. Armenia (2)
5. Australia (52)
6. Austria (2)
7. Bahrain (26)
8. Bangladesh (58)
9. Belarus (4)
10. Belgium (3)
11. Benin (2)
12. Benin Republic (1)
13. Bhutan (1)
14. Bosnia and Herzegovina (1)
15. Botswana (9)
16. Brazil (40)
17. Brunei (1)
18. Bulgaria (1)
19. Burkina Faso (1)
20. Cameroon (1)
Total: 121 countries

Show all countries
Engineering Solid Mechanics
ISSN 2291-8752 (Online) - ISSN 2291-8744 (Print)
Quarterly Publication
Volume 12 Issue 4 pp. 343-352, 2024

Fly ash utilization as support of nano zinc oxide composite catalyst for methanolysis of kapok (Ceiba Pentandra) seed oil Pages 343-352 PDF Download PDF

Authors: Nyoman Puspa Asri, Yohannes Somawiharja, Yustia Wulandari Mirzayanti, Diah Agustina Puspitasari, Rachmad Ramadhan Yogaswara, Jia-Ming Chern

📋 Author Affiliations:
N.P. Asri ORCID 1, Y. Somawiharja1, Y.W. Mirzayanti ORCID 2, D.A. Puspitasari ORCID 3, R.R. Yogaswara ORCID 4, J.-M. Chern5
1 Department of Food Technology, Universitas Ciputra Surabaya, Surabaya, 60219, Indonesia
2 Department of Chemical Engineering, Institut Teknologi Adhi Tama Surabaya (ITATS), Surabaya, 60117, Indonesia
3 Department of Chemical Engineering, Universitas Brawijaya, Malang, 65145, Indonesia
4 Department of Chemical Engineering, Universitas Pembangunan Nasional Veteran Jawa Timur, Surabaya, 60294, Indonesia
5 Department of Chemical Engineering and Biotechnology, Tatung University, 40 Chungshan North Road, 3rd Sec, Taipei, 104, Taiwan
doi 10.5267/j.esm.2024.6.002
2 Source: Scopus
Crossref 3 Source: CrossRef

🔑 Keywords: Biodiesel, Composite catalyst, Coal fly ash, Ceiba pentranda oil, Zinc oxide

Abstract: This study focuses on developing a nano zinc oxide (ZnO) catalyst with fly ash (FA) as a support material for converting kapok seed oil (KSO) into biodiesel. This research aims to study the preparation of nano ZnO/FA solid catalysts and the catalyst's reactivity towards kapok seed oil biodiesel (KSOB) products. The catalysts were synthesized using a modification of the Stober process, which is the co-precipitation, impregnation, and precipitation step co-occurred. The catalyst is prepared on base condition using sodium hydroxide with a solvent of methanol and zinc chloride as a raw material. FA waste was effectively modified with zinc oxide particles to create a high-performance ZnO/FA composite catalyst. Under optimal stoichiometric NaOH and 60% ZnO, the resulting material achieved a remarkable specific surface area of 14.8 m²/gram, indicating its potential for enhanced catalytic activity. The prepared catalyst of nano ZnO/FA achieved successful methanolysis of KSO, with a maximum FAME yield of 61.09% attained at 65°C after 5 hours of reaction time, using a 3% catalyst dose and a KSO: methanol molar ratio of 1:15. The initial success of nano ZnO/FA with kapok seed oil paves the way for further development towards robust catalysts specifically tailored for low-grade oil conversion.

How to cite this paper
APA: Asri, N., Somawiharja, Y., Mirzayanti, Y., Puspitasari, D., Yogaswara, R & Chern, J. (2024). Fly ash utilization as support of nano zinc oxide composite catalyst for methanolysis of kapok (Ceiba Pentandra) seed oil. Engineering Solid Mechanics, 12(4), 343-352.
Chicago/Turabian: Asri, N., Somawiharja, Y., Mirzayanti, Y., Puspitasari, D., Yogaswara, R & Chern, J. 2024. "Fly ash utilization as support of nano zinc oxide composite catalyst for methanolysis of kapok (Ceiba Pentandra) seed oil." Engineering Solid Mechanics 12, no. 4 (2024): 343-352.
AMA: Asri, N., Somawiharja, Y., Mirzayanti, Y., Puspitasari, D., Yogaswara, R & Chern, J. Fly ash utilization as support of nano zinc oxide composite catalyst for methanolysis of kapok (Ceiba Pentandra) seed oil. Engineering Solid Mechanics. 2024;12(4):343-352.

References
AlSharifi, M., & Znad, H. (2019). Development of a lithium-based chicken bone (Li-Cb) composite as an efficient catalyst for biodiesel production. Renewable Energy, 136, 856–864. doi: 10.1016/j.renene.2019.01.052.
Asri, N. P., Machmudah, S., Wahyudiono, W., Suprapto, S., Budikarjono, K., Roesyadi, A., & Goto, M. (2013). Non-Catalytic Transesterification of Vegetables Oil to Biodiesel in Sub-and Supercritical Methanol: A Kinetic’s Study. Bulletin of Chemical Reaction Engineering & Catalysis 7(3), 215–223. doi: 10.9767/bcrec.7.3.4060.215-223.
Asri, N. P., Machmudah, S., Wahyudiono, W., Suprapto, S., Budikarjono, K., & Roesyadi, A., Goto, M. (2013). Palm oil transesterification in sub- and supercritical methanol with heterogeneous base catalyst. Chemical Engineering and Processing: Process Intensification 72, 63–67. doi: 10.1016/j.cep.2013.07.003.
Asri, N. P., Prasetiyo, W. D., Kafidhu, A., Atiqoh, A., Puspitasari, E.A., Hindarso, H., & Suprapto, S. (2020). Transesterification of kapok seed oil (Ceiba pentandra) using heterogeneous catalyst bimetallic oxide of zinc and copper supported by γ-alumina. Materials Science Forum, 988, 87–94. doi: 10.4028/www.scientific.net/msf.988.87.
Asri, N. P., Saraswati, S., Yogaswara, R. R., Puspitasari, D. A, Mirzayanti, Y. W., & Udyani, K. (2021). Functionalization of Multiwall Carbon Nano-Tube Supported Zinc Oxide Solid Acid Catalyst Using Sulfonate Compound for Transesterification of Schleichera Oleosa L Oil. Journal of Physics: Conference Series, 2117(1). doi: 10.1088/1742-6596/2117/1/012038.
Asri, N. P., Saraswati, S., Hindarso, H., Mirzayanti, Y. W., & Yogaswara, R. R. (2021). Study of catalyst support utilization on ZnO-based solid catalyst to its activity at transesterification of Kesambi (Schleichera oleosa) oil. IOP Conference Series: Materials Science and Engineering, 1034(1). doi: 10.1088/1757-899x/1034/1/012059.
Asri, N. P., Yunati, Y., Hindarso, H., & Yogaswara, R. R. (2020). Preparation of Multi-Walled Carbon Nanotubes Supported Zinc Oxide Catalyst for Transesterification of Kesambi (Schleichera oleosa) Oil. IOP Conference Series: Materials Science and Engineering, 742(1). doi: 10.1088/1757-899X/742/1/012034.
Asri, N. P., Saraswati, R., Hindarso, H., Puspitasari, D. A., & Suprapto. 2021. Synthesis of biodiesel from kesambi (Schleichera oleosa L.) oil using carbon nanotube-supported zinc oxide heterogeneous catalyst. IOP Conference Series: Earth and Environmental Science, 749(1). doi: 10.1088/1755-1315/749/1/012048.
Asri, N. P., Soe’eib, S., Poedjojono, B., & Suprapto. 2018. Alumina supported zinc oxide catalyst for production of biodiesel from kesambi oil and optimization to achieve highest yields of biodiesel. Euro-Mediterranean Journal for Environmental Integration, 3(1), 3. doi: 10.1007/s41207-017-0043-8.
Asri, N. P., Yuniati, Y., Hindarso, H., Suprapto, & Yogaswara, R. R. 2020. Biodiesel production from Kesambi (Schleichera oleosa) oil using multi-walled carbon nanotubes supported zinc oxide as a solid acid catalyst. IOP Conference Series: Earth and Environmental Science, 456(1), 012003. doi: 10.1088/1755-1315/456/1/012003.
Asri, N. P., Budikarjono, K., & Roesyadi, A. 2015. Kinetics of Palm Oil Transesterification Using Double Promoted Catalyst CaO/KI/γ-Al2O3. Journal of Engineering and Technological Sciences, 47(4), 353–363. doi: 10.5614/j.eng.technol.sci.2015.47.4.1.
Asri, N. P., Yuniati, Y., Hindarso, H., Suprapto, & Yogaswara, R. R. 2020. Transesterification of kapok seed oil (Ceiba pentandra) using heterogeneous catalyst bimetallic oxide of zinc and copper supported by γ-alumina. Materials Science Forum, 988, 87–94. doi: 10.4028/www.scientific.net/msf.988.87.
Babajide, O., Musyoka, N., Petrik, L., & Ameer, F. (2012). Novel zeolite Na-X synthesized from fly ash as a heterogeneous catalyst in biodiesel production. Catalysis Today, 190(1), 54–60. doi: 10.1016/j.cattod.2012.04.044.
Babajide, O., Petrik, L., Musyoka, N., Amigun, B., & Ameer, F. (2010). Application of coal fly ash as a solid basic catalyst in producing biodiesel. AIChE Annual Meeting Conference Proceedings.
Gurunathan, B., & Ravi, A. (2015). Biodiesel production from waste cooking oil using copper doped zinc oxide nanocomposite as heterogeneous catalyst. Bioresource Technology, 188, 124–127. doi: 10.1016/j.biortech.2015.01.012.
He, P. Y., Zhang, Y. J., Chen, H., Han, Z. C., & Liu, L. C. (2019). Low-energy synthesis of kaliophilite catalyst from circulating fluidized bed fly ash for biodiesel production. Fuel, 257, 116041. doi: 10.1016/j.fuel.2019.116041.
Helwani, Z., Ramli, M., Saputra, E., Putra, Y. L., Simbolon, D. F., Othman, M. R., & Idroes, R. (2020). Composite catalyst of palm mill fly ash-supported calcium oxide obtained from eggshells for transesterification of off-grade palm oil. Catalysts, 10(7). doi: 10.3390/catal10070724.
Istadi, I., Anggoro, D. D., Buchori, L., Rahmawati, D. A., & Intaningrum, D. (2015). Active Acid Catalyst of Sulphated Zinc Oxide for Transesterification of Soybean Oil with Methanol to Biodiesel. Procedia Environmental Science, 23, 385–393. doi: 10.1016/j.proenv.2015.01.055.
Katara, S., Kabra, S., Goyal, D., Hada, R., Sharma, A., & Rani, A. (2020). Fly ash to solid base catalyst: Synthesis, characterization and catalytic application. Materials Today: Proceedings, 42, 1409–1416. doi: 10.1016/j.matpr.2021.01.148.
Khan, T. M. Y. (2020). A Review of Performance-Enhancing Innovative Modifications in Biodiesel Engines. Energies, 13(17), 4395. doi: 10.3390/en13174395.
Kusumaningtyas, R. D., Utomo, M. Y. A., Nurjanah, P. R., & Widjanarko, D. 2020. Synthesis of biodiesel from kapok (Ceiba pentandra L.) seed oil through ultrasound-enhanced transesterification reaction. AIP Conference Proceedings 2217(1), 2–11. doi: 10.1063/5.0000609.
Malpani, S. K., & Rani, A. (2019). A Greener Route for Synthesis of Fly Ash Supported Heterogeneous Acid Catalyst. Materials Today: Proceedings, 9, 551–559. doi: 10.1016/j.matpr.2018.10.375.
Mandolesi de Araújo, C. D., de Andrade, C. C., de Souza e Silva, E., & Dupas, F. A. (2013). Biodiesel production from used cooking oil: A review. Renewable and Sustainable Energy Reviews, 27, 445–452. doi: 10.1016/j.rser.2013.06.014.
Mukenga, M. (2012). Biodiesel production over supported Zinc Oxide nanoparticles. University of Johannesburg.
Muñoz, R., Gonzales, A., Valdebenito, F., Ciudad, G., Navia, R., Pecchi, G., & Azocar, L. (2020). Fly ash as a new versatile acid-base catalyst for biodiesel production. Renewable Energy, 162, 1931–1939. doi: 10.1016/j.renene.2020.09.099.
Nair, P., Singh, B., Upadhyay, S., & Sharma, Y. C. (2012). Synthesis of biodiesel from low FFA waste frying oil using calcium oxide derived from mereterix as a heterogeneous catalyst. Journal of Cleaner Production, 29–30, 82–90. doi: 10.1016/j.jclepro.2012.01.039.
Olutoye, M. A., & Hameed, B. H. (2011). Synthesis of fatty acid methyl ester from used vegetable cooking oil by solid reusable Mg1-xZn1+xO2 catalyst. Bioresource Technology, 102(4), 3819–3826. doi: 10.1016/j.biortech.2010.11.100.
Perhutani. (2022). Optimalkan Pemanfaatan Hutan Dengan Budidaya Kapuk Randu, Perhutani Tandatangani Mou Bersama RWH. Retrieved from https://www.perhutani.co.id/optimalkan-pemanfaatan-hutan-dengan-budidaya-kapuk-randu-perhutani-tandatangani-mou-bersama-rwh/. Access April 8, 2022.
Ponappa, K., Velmurugan, V., Franco, P. A., Kannan, T. R., & Ragurajan, R. (2016). Optimization of Biodiesel Production from Ceiba Pentandra (Kapok Seed Oil) Using Response Surface Methodology Assisted by Ultrasonic Energy Method. International Journal of Chemical Technology Research, 9(5), 794–803.
Putri, E. M. M., Rachimoellah, M., Santoso, N., & Pradana, F. (2012). Biodiesel production from kapok seed oil (Ceiba pentandra) through the transesterification process by using CaO as catalyst. Global Journal of Research in Engineering and Chemical Engineering, 12(2), 6–11.
Risdanareni, P., Puspitasari, P., & Januarti Jaya, E. (2017). Chemical and Physical Characterization of Fly Ash as Geopolymer Material. MATEC Web of Conferences, 97. doi: 10.1051/matecconf/20179701031.
Roy, T., Sahani, S., & Sharma, Y. C. (2020). Green synthesis of biodiesel from Ricinus communis oil (castor seed oil) using potassium promoted lanthanum oxide catalyst: kinetic, thermodynamic and environmental studies. Fuel, 274, 117644. doi: 10.1016/j.fuel.2020.117644.
Sharma, Y. C., & Singh, B. (2010). A hybrid feedstock for a very efficient preparation of biodiesel. Fuel Processing Technology, 91, 1267–1273. doi: 10.1016/j.fuproc.2010.04.008.
Sharma, Y. C., Singh, B., & Korstad, J. (2010). High Yield and Conversion of Biodiesel from a Nonedible Feedstock (Pongamia pinnata). Journal of Agricultural and Food Chemistry, 58(1), 242–247. doi: 10.1021/jf903227e.
Widjanarko, D., Kusumaningtyas, R. D., & Fathoni, A. A. (2020). Alteration of Biodiesel Properties and Automotive Diesel Engine Performance due to Temperature Variation of the Transesterification Process. Jurnal Rekayasa Kimia dan Lingkungan, 15(2) 90–98. doi: 10.23955/rkl.v15i2.16007.
Yusuff, A. S., Yusuff., A. S., Bhonsle, A. K., Trivedi, J., Bangwal, D. P., Singh, L. P., & Atray, N. (2021). Synthesis and characterization of coal fly ash supported zinc oxide catalyst for biodiesel production using used cooking oil as feed. Renewable Energy, 170, 302–314. doi: 10.1016/j.renene.2021.01.101.
Yusuff, A. S., & Bello, K. A. (2019). Synthesis of fatty acid methyl ester via transesterification of waste frying oil by a zinc-modified pumice catalyst: Taguchi approach to parametric optimization. Reaction Kinetics, Mechanisms and Catalysis 128(2), 739–761. doi: 10.1007/s111
  • 51
  • 1
  • 2
  • 3
  • 4
  • 5

📚 Journal: Engineering Solid Mechanics | 📅 Year: 2024 | 📖 Volume: 12 | 📄 Issue: 4 | 👁️ Views: 1030 | 📊 Crossref: 3

Related Articles:
  • Synthesis of bio-based poly limonene oxide with green catalyst
  • Mesoporous MCM-41 modified with Cu(II) for indole removal: A Taguchi design
  • Starch functionalization of trimetallic W-Mg-Al oxide for oxidative desulphurisation of dibenzothiophene
  • One-pot solvent free synthesis of dihydropyrimidinones using calcined Mg/Fe hydrotalcite catalyst
  • Ultrasound assisted synthesis of enaminones using Nickel oxide

📝 Ready to share your research?

Engineering Solid Mechanics is accepting new submissions for upcoming issues. Join our community of authors and publish your work with us.

✓ Open access
✓ Rigorous peer review
✓ Fast publication
📤 Submit Your Manuscript →

📖 Author Guidelines

® 2010-2026 GrowingScience.Com