Enhancing the dynamic mechanical properties of thermoplastic elastomers: A study on polypropylene /natural rubber blends

Owen, E.; Kooi, O.; Ebhodaghe, O.; Hilary, I.

Growing Science » Current Chemistry Letters » Enhancing the dynamic mechanical properties of thermoplastic elastomers: A study on polypropylene /natural rubber blends

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Current Chemistry Letters

ISSN 1927-730x (Online) - ISSN 1927-7296 (Print) Quarterly Publication Volume 13 Issue 3 pp. 633-640 , 2024

Enhancing the dynamic mechanical properties of thermoplastic elastomers: A study on polypropylene /natural rubber blends Pages 633-640 Download PDF

Authors: Egharevba Owen, Ong Siew Kooi, Okieimen Felix Ebhodaghe, Ifijen Ikhazuagbe Hilary

DOI: 10.5267/j.ccl.2023.11.002

Keywords: Polypropylene, Natural rubber, Thermoplastic elastomer, Mechanical properties

Abstract: The aim of this study was to investigate the modifications of the mechanical properties of polypropylene (PP) by incorporating elastomers, while considering the impact on its stiffness. Specifically, the research focused on determining the optimal loading of elastomer to achieve desirable properties and exploring the influence of these processes on the morphology and mechanical behavior of the prepared blends. Thermoplastic elastomers (TPEs) consisting of polypropylene and natural rubber (PP/NR) were prepared using a melt-mixing process, and the mechanical properties of the blends were evaluated. The stress-strain properties of the blends revealed a successful modification of PP, transforming it from a stiff and strong thermoplastic into a stiff and tough thermoplastic elastomer when 10% NR was included in the PP matrix. As the loading of NR increased, a reduction in tensile strength (TS) and modulus (E) of the blends was observed, while elongation at break (EB) increased. The flexural strength of unmodified PP was 45.9 MPa, which decreased with increasing NR loading. Similarly, the impact strength of unmodified PP was 25.8 KJ/m², whereas the values for 10%, 20%, 30%, and 40% NR inclusion were 30.8, 24.3, 20.6, and 15.2 KJ/m², respectively. The melt flow index (MFI) of unmodified PP was 14.1 g/10 min, while the values for 10%, 20%, 30%, and 40% NR inclusion were 19.4, 15.7, 11.6, and 10.2 g/10 min, respectively. The best combination of mechanical properties was observed at 10% NR inclusion in the PP matrix. The micrograph of the blends, as observed from SEM micrographs, supported the modification of PP, resulting in the production of TPE with observable adhesion sites, indicating good compatibility between the components. In a nutshell, a significant 47% increase in impact strength was achieved through the modification process.

How to cite this paper

 Owen, E., Kooi, O., Ebhodaghe, O & Hilary, I. (2024). Enhancing the dynamic mechanical properties of thermoplastic elastomers: A study on polypropylene /natural rubber blends.Current Chemistry Letters, 13(3), 633-640.

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