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Growing Science » Current Chemistry Letters » Interaction of two heterocyclic Schiff bases derived from 2-acetyl pyridine on mild steel in hydrochloric acid: Physicochemical and corrosion inhibition investigations

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Current Chemistry Letters

ISSN 1927-730x (Online) - ISSN 1927-7296 (Print)
Quarterly Publication
Volume 9 Issue 1 pp. 19-30 , 2020

Interaction of two heterocyclic Schiff bases derived from 2-acetyl pyridine on mild steel in hydrochloric acid: Physicochemical and corrosion inhibition investigations Pages 19-30 Right click to download the paper Download PDF

Authors: M. Paulson Binsi, Thomas K. Joby, K. Ragi, Varghese C. Sini, Johnson Reeja

DOI: 10.5267/j.ccl.2019.6.005

Keywords: (Z)-N-(5-(Dichloromethylene)-2-oxoimidazolidin-4-ylidene)-N'-substituted sulphonamides, Heterocyclization, Anticancer Activity

Abstract: Two heterocyclic Schiff bases namely (E)-2-(1-(2-phenylhydrazono)ethyl)pyridine (or 2-acetyl pyridine phenyl hydrazone) (2APPH) and (E)-2-(1-triazylidineethyl)pyridine (or 2-acetyl pyridine semicarbazone) (2APSC) were synthesized, characterized and their corrosion inhibition behaviour as well as mechanism of inhibition were investigated by different techniques. Structural characterization includes NMR, Mass, IR and UV-visible spectroscopy and elemental analysis. Corrosion inhibition behaviour of aforesaid compounds on mild steel in 1M hydrochloric acid was examined by electrochemical methods including potentiodynamic polarization analysis and electrochemical impedance spectroscopic techniques. The mechanism of corrosion inhibition was explored and supplemented by adsorption and surface morphological studies. Quantum mechanical investigations on corrosion behaviour of compounds were also conducted and satisfying correlation was noticed between the results of corrosion measurement methods and quantum mechanical evaluations.

How to cite this paper
Binsi, M., Joby, T., Ragi, K., Sini, V & Reeja, J. (2020). Interaction of two heterocyclic Schiff bases derived from 2-acetyl pyridine on mild steel in hydrochloric acid: Physicochemical and corrosion inhibition investigations.Current Chemistry Letters, 9(1), 19-30.

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Journal: Current Chemistry Letters | Year: 2020 | Volume: 9 | Issue: 1 | Views: 1891 | Reviews: 0

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