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Growing Science » Current Chemistry Letters » Electrochemical and AFM studies on adsorption behavior of a Polynuclear Schiff Base at carbon steel in HCl medium

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Current Chemistry Letters

ISSN 1927-730x (Online) - ISSN 1927-7296 (Print)
Quarterly Publication
Volume 4 Issue 2 pp. 67-76 , 2015

Electrochemical and AFM studies on adsorption behavior of a Polynuclear Schiff Base at carbon steel in HCl medium Pages 67-76 Right click to download the paper Download PDF

Authors: Shaju K Shanmughan, Joby Thomas Kakkassery, Vinod P Raphael, Nimmy Kuriakos

DOI: 10.5267/j.ccl.2015.2.001

Keywords: Adsorption, AFM, Carbon Steel, Corrosion Inhibitors, Impedance

Abstract: The adsorption behavior of a potential polynuclear Schiff base, (s)-2-(anthracen-9(10H)-ylideneamino)-3-phenyl propanoic acid (A9Y3PPA) on carbon steel (CS) in 1M hydrochloric acid solution has been investigated using weight loss measurements, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization studies. The surface morphology of the carbon steel specimens in the presence and absence of the inhibitor was evaluated by AFM analysis. The corrosion inhibition efficiencies of parent amine and parent ketone on carbon steel in 1M HCl solution have also been investigated using weight loss studies. The adsorption of A9Y3PPA obeys Langmuir adsorption isotherm. Thermodynamic parameters (Kads, ∆G0ads) were calculated using the adsorption isotherm. Activation parameters of the corrosion process (Ea, ∆H* and ∆S*) were also calculated from the corrosion rates obtained from temperature studies. Tafel plot analysis revealed that A9Y3PPA acts as a mixed type inhibitor. A probable inhibition mechanism was also proposed.

How to cite this paper
Shanmughan, S., Kakkassery, J., Raphael, V & Kuriakos, N. (2015). Electrochemical and AFM studies on adsorption behavior of a Polynuclear Schiff Base at carbon steel in HCl medium.Current Chemistry Letters, 4(2), 67-76.

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Journal: Current Chemistry Letters | Year: 2015 | Volume: 4 | Issue: 2 | Views: 2289 | Reviews: 0

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