This work presents a comprehensive synthesis method for the development of a new hyperbranched unsaturated polyester resin (HUPR). The resin is synthesized by modifying dehydrated castor oil fatty acid (DCOFA) with methyl methacrylate (MMA) and styrene, dicyclopentadiene-maleate (DCPD-M), and trimethylol propane diallyl ether (TMPDE). The synthesis process involves the radical addition reaction of DCOFA with MMA and styrene, followed by the addition of DCPD-M and TMPDE to form a HUPR. The resulting resin exhibits enhanced properties, making it a promising candidate for car body putty in the polymer industry.

Hyperbranched polyester polyols have emerged as a promising candidate for polyurethane coatings due to their unique structure and properties. In this context, this paper aims to synthesize a new hyperbranched polyester polyol and evaluate its potential as a polyol for polyurethane coating applications. In this study, the synthesis of hyperbranched polyester polyol involves the reaction between a multifunctional alcohol and a multifunctional carboxylic acid or anhydride. It is further modified by incorporating 2-hydroxyethyl methacrylate and styrene. The properties of the polyester polyol were characterized using various analytical techniques, including FTIR, NMR, SEM and TGA. This paper also provides a discussion on the potential applications of the synthesized hyperbranched polyester polyol in several industries such as automotive, aerospace and construction.

The immobilized NaHSO4·H2O on activated charcoal was used as a highly efficient promoter system for facile N-formylation of amines with ethyl formate. All reactions were carried out in refluxing ethyl formate (54 ?C) under mild conditions within 10-100 min to afford the product formamides in high to excellent yields (80-94%).

During the past few years, operations research applications in health care operation management have grown quickly. On the other hand blood as a perishable, valuable and lifesaving product is one important asset of any healthcare center. Therefore, designing a blood supply network comes to importance. It also should be noted that a blood supply chain comprises specific modifications. This study intends to locate blood bank components in a network, and to determine the allocations among the network components. The supply chain components considered in this study are donation sites, testing and processing labs, blood banks, and demand points. It is known that demand centers such as hospitals and clinics highly depend on blood products and any deficiency in procurement can even result in a person’s death. Thus, in the last layer of the considered network a transshipment sub-network is considered between demand points. Most of the intricacies in problem formulation of blood supply chain are regarded in this study; cases such as blood wastage, blood product decomposition in lab facilities, and transshipments between demand points. Due to the fact that for such an important and lifesaving supply chain the aim would go beyond minimizing cost, another objective function is presented for the problem. Hence, to obtain a Pareto solution for both objective functions ?-constraint method is utilized. Finally, to demonstrate the applicability of the problem, the model is implemented on a number of problem sets.