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1.

3-Formylpyrazolo[1,5-a]pyrazine-4-carboxylates as new bielectrophilic reagents in the cascade synthesis of polyazaacenaphthylene and polyazaacetanthrylene derivatives Pages 399-406 Right click to download the paper Download PDF

Authors: Nazar Tsyzoryk, Khrystyna Loza, Andriy Bolbut, Svitlana Shishkina, Maryna Stasevych, Mykhailo Vovk

DOI: 10.5267/j.ccl.2025.5.002

Keywords: Pyrazolo[1, 5-a]pyrazine-4-carboxylates, 3-formylpyrazolo[1, 5-a]pyrazine-4-carboxylates, 1, 5-bielectrophilic reagents, Diaminoalkanes, Cascade reactions, Pentaazacyclopenta[d]acenaphthalenes, Pentaazaaceanthrylenes

Abstract:
It has been shown that 3-formylpyrazolo[1,5-a]pyrazine-4-carboxylates obtained by the selective formylation of pyrazolo[1,5-a]pyrazine-4-carboxylates react with 1,2-ethanediamine or 1,3-propanediamine in methanol at room temperature to give pentaazacyclopenta[d]acenaphthalenes or pentaazaaceanthrylenes.
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Journal: CCL | Year: 2025 | Volume: 14 | Issue: 3 | Views: 307 | Reviews: 0

 

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