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Growing Science » Authors » Hossein Ghafuri

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1.

Transition metal-free oxidation of benzylic alcohols to carbonyl compounds by hydrogen peroxide in the presence of acidic silica gel Pages 27-32 Right click to download the paper Download PDF

Authors: Hossein Ghafuri

DOI: 10.5267/j.ccl.2014.11.001

Keywords: Acidic silica gel, Carbonyl compounds, Hydrogen peroxide, Oxidation

Abstract:
Oxidation of alcohols to carbonyl compounds has become an important issue in the process industry as well as many other applications. In this method, various benzylic alcohols were successfully converted to corresponding aldehydes and ketones under transition metal-free condition using hydrogen peroxide in the presence of some amount of catalytic acidic silica gel. Silica gel is inexpensive and available. One of the most important features of this method is its short reaction time.
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Journal: CCL | Year: 2015 | Volume: 4 | Issue: 1 | Views: 3050 | Reviews: 0

 
2.

Fast and green synthesis of biologically important quinoxalines with high yields in water Pages 183-188 Right click to download the paper Download PDF

Authors: Hossein Ghafuri

Keywords: 1-2-Diketones, Biological activity, Diamines, Quinoxaline, Water

Abstract:
Optimal method were developed for the green synthesis of quinoxaline derivatives based on the highly efficient and simple condensation reaction of various aromatic 1,2-diketones and 1,2-diamines in nearly quantitative yields in water. In this method we did not use any catalyst. The very mild reaction conditions, the high yields of the products, and the absence of any catalyst make this methodology an efficient and green route for synthesis of quinoxalines.
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Journal: CCL | Year: 2014 | Volume: 3 | Issue: 3 | Views: 2691 | Reviews: 0

 

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