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Growing Science » Authors » D. Kapuściński

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1.

Electronic properties of complexes derived from imidazolium cations and carbonyl compounds and their reactivity in synthesis of bisphenol derivatives in the light of CDFT/MEDT approach Pages 771-776 Right click to download the paper Download PDF

Authors: E. Dresler, E. Nowakowska-Bogdan, W. Łącka, M. Ząbkowska, D. Kapuściński, R. Jasiński

doi 10.5267/j.ccl.2025.8.006

🔑 Keywords: Reactivity indexes theory, Electrophilic substitution reactions, Bis-phenols, Ionic liquid

Abstract:
In terms of Domingo terminology, complexes of carbonyl compounds with imidazolium cations should be considered as extremely strong electrophiles. Reactions of these compounds with phenol yielding bis-phenols follow a polar mechanism. Furthermore, the discussion based on the theory of reactivity indexes can be used to predict the reactivity of respective electrophiles and regio-orientation in EAS reactions, the first stage of bis-phenol synthesis, kinetically rate-limiting for the whole process.
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Journal: CCL | Year: 2025 | Volume: 14 | Issue: 4 | Views: 287

 

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